764949
2,3-萘酞菁锡(II)
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关于此项目
经验公式（希尔记法）:
C48H24N8Sn
化学文摘社编号:
分子量:
831.47
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI
1S/C48H24N8.Sn/c1-2-10-26-18-34-33(17-25(26)9-1)41-49-42(34)54-44-37-21-29-13-5-6-14-30(29)22-38(37)46(51-44)56-48-40-24-32-16-8-7-15-31(32)23-39(40)47(52-48)55-45-36-20-28-12-4-3-11-27(28)19-35(36)43(50-45)53-41;/h1-24H;/q-2;+2
SMILES string
[SnH2]1n2c3nc4nc(nc5n1c(nc6nc(nc2c7cc8ccccc8cc37)c9cc%10ccccc%10cc69)c%11cc%12ccccc%12cc5%11)c%13cc%14ccccc%14cc4%13
InChI key
SCYVSSHNBKWAKE-UHFFFAOYSA-N
form
powder
mp
>400 °C
λmax
735 nm in chloronaphthalene, 789 nm in chloronaphthalene, 830 nm in chloronaphthalene
General description
Tin (II) 2,3-naphthalocyanine is widely used in organic photodiodes and solar cells since it exhibits very strong absorption in the infrared region (IR).This increases the power conversion efficiencies (PCE) of organic photovoltaic (OPV) cells since it absorbs light in the near infrared and infra-red portions of the electromagnetic spectrum which accounts for 50% of the solar photon flux.
Application
Used in the synthesis of naphthalocyanine based nano-crystalline thin films which show near IR absorption and high extinction coefficient inorganic thin film devices.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Enhancement of photovoltaic characteristics of nanocrystalline 2, 3-naphthalocyanine thin film-based organic devices
Farag, A. A. M., Osiris, W. G., & Ammar, A. H.
Applied Surface Science, 259, 600-609 (2012)
N C Yates et al.
Journal of photochemistry and photobiology. B, Biology, 4(4), 379-390 (1990-03-01)
Metal naphthalocyanine complexes (MNCSs) absorb light in the near-IR spectral region (760 nm) where tissue penetration is optimal and they have been proposed as agents for photodynamic therapy (PDT). Sulphonated derivatives of tris-(2,3-naphthalocyanato) bis-chloroaluminium(III) and zinc(II) with various degrees of
Tin naphthalocyanine complexes for infrared absorption in organic photovoltaic cells
Pandey, R., Kerner, R. A., Menke, S. M., Holst, J., Josyula, K. V., & Holmes, R. J.
Organic Electronics, 14(3), 804-808 (2013)
Elena Jakubikova et al.
The journal of physical chemistry. A, 115(33), 9265-9272 (2011-08-02)
Tin naphthalocyanine molecules display strong absorption in the infrared region (IR), making them ideal as components of organic photodiodes and solar cells. We use density functional theory and time-dependent density functional theory (TD-DFT) at the B3LYP level to study the
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