765910
三（3,5-二甲基-1-吡唑基）硼氢化钾
97%, solid
别名:
Potassium hydrotris(3,5-dimethylpyrazol-1-yl)borate, Scorpionates, Tp ligand
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关于此项目
经验公式（希尔记法）:
C15H22BKN6
化学文摘社编号:
分子量:
336.28
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22
MDL number:
Assay:
97%
Form:
solid
产品名称
三（3,5-二甲基-1-吡唑基）硼氢化钾, 97%
SMILES string
[K+].Cc1cc(C)n(n1)[BH-](n2nc(C)cc2C)n3nc(C)cc3C
InChI
1S/C15H22BN6.K/c1-10-7-13(4)20(17-10)16(21-14(5)8-11(2)18-21)22-15(6)9-12(3)19-22;/h7-9,16H,1-6H3;/q-1;+1
InChI key
NTWZGFNSHCFHIJ-UHFFFAOYSA-N
assay
97%
form
solid
mp
292-301 °C
Quality Level
Application
Scorpionate ligand
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Brendan J Liddle et al.
The Journal of organic chemistry, 72(25), 9794-9797 (2007-11-13)
The preparation of three tris(pyrazolyl)toluidines from trifluoromethylaniline reagents is described that likely takes advantage of (quinoidal) resonance-stabilized activation of the C-F bonds. Subsequent transformations lead to two additional (for a total of five new) tris(pyrazolyl)methylaryls. This simple reaction is remarkable
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