767662
Chloro(1-naphthyl)bis(triphenylphosphine)nickel(II)
97%
别名:
trans-Chloro(1-naphthyl)bis(triphenylphosphine)nickel(II)
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关于此项目
经验公式（希尔记法）:
C46H37ClNiP2
化学文摘社编号:
分子量:
745.88
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22
SMILES string
Cl[Ni]c1cccc2ccccc12.c3ccc(cc3)P(c4ccccc4)c5ccccc5.c6ccc(cc6)P(c7ccccc7)c8ccccc8
InChI
1S/2C18H15P.C10H7.ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-6-10-8-4-3-7-9(10)5-1;;/h2*1-15H;1-7H;1H;/q;;;;+1/p-1
InChI key
BFFKUFPCFQLCFH-UHFFFAOYSA-M
assay
97%
form
powder
reaction suitability
core: nickel, reagent type: catalyst
mp
187-191 °C
storage temp.
20-25°C
Application
Nickel Catalyst for Carbon-Nitrogen Coupling
signalword
Danger
hcodes
Hazard Classifications
Carc. 1B - Skin Sens. 1
存储类别
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Jin-Hua Huang et al.
Organic letters, 13(14), 3750-3753 (2011-06-22)
The amination of triaryl phosphates was achieved using a Ni(II)-(σ-Aryl) complex/NHC catalyst system in dioxane at 110 °C in the presence of NaH as base. Electron-neutral, -rich, and -deficient triaryl phosphates were coupled with a wider range of amine partners
商品
Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.
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