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Merck
CN

771953

exo-5-Norbornene-2-methanol

≥99% (exo)

别名:

exo-5-Norbornenyl methyl alcohol

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关于此项目

经验公式(希尔记法):
C8H12O
化学文摘社编号:
分子量:
124.18
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12162002
MDL number:
Assay:
≥99% (exo)
Form:
liquid
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InChI

1S/C8H12O/c9-5-8-4-6-1-2-7(8)3-6/h1-2,6-9H,3-5H2/t6-,7+,8?/m0/s1

SMILES string

OCC1C[C@@H]2C[C@H]1C=C2

InChI key

LUMNWCHHXDUKFI-KJFJCRTCSA-N

assay

≥99% (exo)

form

liquid

refractive index

n20/D 1.499

bp

200-205/760 mmHg

density

1.030 at 25 °C

Quality Level

General description

Exo-5-Norbornene-2-methanol is a norbornene derivative which is widely used as a monomer in the synthesis of polynorbornenes by vinyl polymerisation or ring opening methathesis polymerisation (ROMP). They are also used as a monomer or an intermediate in the synthesis of photoresist materials. This material is also widely used as an intermediate in the synthesis of pharmaceutically and biologically active compounds.

Application

Used as a monomer in the synthesis of polynorbornenes by ring opening metathesis polymerisation.

Features and Benefits

  • Produces polymers with high thermal stability and transparency which are useful for optical applications.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

195.0 °F

flash_point_c

90.55 °C

法规信息

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Stereo-Selective Synthesis of 5-Norbornene-2-exo-carboxylic Acid-Rapid Isomerization and Kinetically Selective Hydrolysis.
Kanao, M., Otake, A., Tsuchiya, K., & Ogino, K.
International Journal of Organic Chemistry, 2, 26-30 (2012)
Water-soluble polymers from acid-functionalized norbornenes
Lienkamp, K., Kins, C. F., Alfred, S. F., Madkour, A. E., & Tew, G. N.
Journal of Polymer Science Part A: Polymer Chemistry, 47(5), 1266-1273 (2009)

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