产品名称
三(2,2,2-三氟乙基)硼酸酯, 97%
InChI key
DIEXQJFSUBBIRP-UHFFFAOYSA-N
SMILES string
FC(F)(F)COB(OCC(F)(F)F)OCC(F)(F)F
InChI
1S/C6H6BF9O3/c8-4(9,10)1-17-7(18-2-5(11,12)13)19-3-6(14,15)16/h1-3H2
assay
97%
form
liquid
refractive index
n/D 1.298 (lit.)
density
1.430 g/mL at 25 °C
functional group
fluoro
Quality Level
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Application
试剂可促进羧酸和胺在热和微波条件下直接生成酰胺。
signalword
Warning
hcodes
Hazard Classifications
Flam. Liq. 3
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
109.9 °F
flash_point_c
43.3 °C
法规信息
危险化学品
此项目有
Rachel M Lanigan et al.
The Journal of organic chemistry, 78(9), 4512-4523 (2013-04-17)
B(OCH2CF3)3, prepared from readily available B2O3 and 2,2,2-trifluoroethanol, is as an effective reagent for the direct amidation of a variety of carboxylic acids with a broad range of amines. In most cases, the amide products can be purified by a
Pavel Starkov et al.
Organic & biomolecular chemistry, 9(5), 1320-1323 (2011-01-08)
Simple borates serve as effective promoters for amide bond formation with a variety of carboxylic acids and amines. With trimethyl or tris(2,2,2-trifluoroethyl) borate, amides are obtained in good to excellent yield and high purity after a simple work-up procedure. Tris(2,2,2-trifluoroethyl)
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