791105
Zinc chloromethanesulfinate
95% (H-NMR)
别名:
Baran MCMS Reagent
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关于此项目
经验公式（希尔记法）:
C2H4Cl2O4S2Zn
化学文摘社编号:
分子量:
292.48
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352101
MDL number:
Assay:
95% (H-NMR)
Form:
solid
InChI
1S/2CH3ClO2S.Zn/c2*2-1-5(3)4;/h2*1H2,(H,3,4);/q;;+2/p-2
SMILES string
ClCS(O[Zn]OS(CCl)=O)=O
InChI key
HEKATMPPXNXYJU-UHFFFAOYSA-L
assay
95% (H-NMR)
form
solid
reaction suitability
reaction type: C-C Bond Formation, reagent type: catalyst
reaction type: C-H Activation, reagent type: diversification reagent
mp
190-195 °C
functional group
chloro, sulfinic acid
storage temp.
2-8°C
Quality Level
Application
Zinc chloromethanesulfinate (MCMS) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.1
Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles
Learn More at the Professor and Product Portal of Professor Phil S. Baran.
Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles
Learn More at the Professor and Product Portal of Professor Phil S. Baran.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Journal of the American Chemical Society
O'Hara,F.; et. al.
Journal of the American Chemical Society, 135, 12122-12134 null
Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles
Fujiwara, Y.; et al.
Nature, 492, 95-100 (2013)
商品
Rapidly diversify (hetero)aromatic scaffolds for chemical industry needs amid resource and time constraints, ensuring efficiency.
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