798320
2-Bromo-6-(trimethylsilyl)phenyl triflate
95%
别名:
Garg 3-Bromobenzyne Precursor
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关于此项目
经验公式（希尔记法）:
C10H12BrF3O3SSi
化学文摘社编号:
分子量:
377.25
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Assay:
95%
Form:
liquid
Quality Segment
assay
95%
form
liquid
refractive index
n
density
1.482 g/L at 25 °C
functional group
bromo, fluoro, triflate
storage temp.
2-8°C
SMILES string
O=S(OC1=C([Si](C)(C)C)C=CC=C1Br)(C(F)(F)F)=O
InChI
1S/C10H12BrF3O3SSi/c1-19(2,3)8-6-4-5-7(11)9(8)17-18(15,16)10(12,13)14/h4-6H,1-3H3
InChI key
ZNKAHJCGEPVEBA-UHFFFAOYSA-N
Application
Synchronous Ar-F and Ar-Sn Bond Formation Through Fluorostannylation of Arynes
Continuous-Flow Synthesis of Trimethylsilylphenyl Perfluorosulfonate Benzyne Precursors
Continuous-Flow Synthesis of Trimethylsilylphenyl Perfluorosulfonate Benzyne Precursors
Bromosilyltriflate has been shown to be a useful precursor for the generation of a bromobenzyne intermediate. The bromobenzyne intermediate can be generated in the presence of cesium or potassium fluoride and can be trapped with various dipolariphiles.
警示词
Danger
危险代码
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
怎么回事？
WGK 3
闪点 (F)
Not applicable
闪点 (°C)
Not applicable