802166
2-（吡啶-2-基）异丙胺
95% (GC)
别名:
PIP, PIP导向基团, Shi辅基
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关于此项目
经验公式（希尔记法）:
C8H12N2
化学文摘社编号:
分子量:
136.19
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
产品名称
2-（吡啶-2-基）异丙胺, 95% (GC)
InChI
1S/C8H12N2/c1-8(2,9)7-5-3-4-6-10-7/h3-6H,9H2,1-2H3
SMILES string
NC(C)(C)C1=CC=CC=N1
InChI key
DQSQBZXDMHDHEO-UHFFFAOYSA-N
description
Fp: 175°F
assay
95% (GC)
form
liquid
reaction suitability
reagent type: catalyst
reagent type: ligand
reaction type: C-H Activation
refractive index
n/D 1.516
density
0.9800 g/mL at 25 °C
functional group
amine
Quality Level
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Application
Shi助剂是一种通过铜介导的C-H 活化而使芳烃羟基化的导向基团。这种辅基可以通过酸介导的水解作用除去，并且已经证明可以进行克级规模的处理。
General description
2-（吡啶-2-基）异丙基胺（PIP-胺）是一种叔胺。由PIP-胺已开发出可用于C-H键官能化的双齿导向基团。
Other Notes
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
175.0 °F
flash_point_c
79.44 °C
Xin Li et al.
Organic letters, 16(15), 3904-3907 (2014-07-17)
A copper-mediated C-H hydroxylation of arenes and heteroarenes using our newly developed PIP directing group has been developed. This procedure is scalable and compatible with a wide range of functional groups and heteroarenes, providing an operationally simple protocol for the
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