SnAP 3-Spiro-(4-Pip) M试剂

Name: SnAP 3-Spiro-(4-Pip) M试剂
Brand: ALDRICH

别名:

tert-butyl 4-amino-4-(((tributylstannyl)methoxy)methyl) piperidine-1-carboxylate

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所有图片(2)

About This Item

经验公式（希尔记法）:

C₂₄H₅₀N₂O₃Sn

分子量:

533.38

MDL编号:

MFCD29905051

UNSPSC代码:

12352103

PubChem化学物质编号:

329768846

NACRES:

NA.22

表单

liquid

质量水平

100

官能团

ether

储存温度

−20°C

SMILES字符串

CCCC[Sn](CCCC)(COCC1(CCN(C(OC(C)(C)C)=O)CC1)N)CCCC

InChI

1S/C12H23N2O3.3C4H9.Sn/c1-11(2,3)17-10(15)14-7-5-12(13,6-8-14)9-16-4;3*1-3-4-2;/h4-9,13H2,1-3H3;3*1,3-4H2,2H3;

InChI key

XZUSOLFDFJLEMZ-UHFFFAOYSA-N

一般描述

SnAP (Sn amino protocol) reagents have been developed by Professor Dr. Jeffrey Bode and co-workers. (These reagents are useful for the preparation of medium-ring (6-9 membered) saturated N-heterocycles, including bicyclic and spirocyclic structures.) SnAP reagents are stable and easy to handle in laboratories. They can be prepared from simple raw materials.

应用

SnAP Reagents provide a one-step route, in tandem with various aldehyde substrates, to saturated N-heterocycles. The synthesis of N-heterocycles through SnAP Reagents requires mild reaction conditions, and aldehydes bearing aryl, heteroaryl, glyoxyl, aliphatic, and halogenated groups are well tolerated. This product was introduced in collaboration with the Bode Research Group

SnAP 3-Spiro-(4-Pip) M Reagent may be used in the preparation of unprotected, saturated N-heterocyclic compounds.

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