81801
1-丙基磷酸酐 溶液
technical, ~50% in DMF
别名:
1-丙基磷酸环酐 溶液, PPACA, T3P®, 丙基磷酸三环酸酐 溶液
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关于此项目
经验公式（希尔记法）:
C9H21O6P3
CAS Number:
分子量:
318.18
Beilstein:
5079255
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
一般描述
Propylphosphonic anhydride is a highly reactive cyclic anhydride that is commonly used as a coupling agent and water scavenger.
应用
Coupling reagent for peptide synthesis; Preparation of other amides; Synthesis of esters (depsipeptides)
特点和优势
Some of its unique features include:
- Broad functional group tolerance
- Low epimerization tendency
- By-products are water-soluble
- High yield and purity
法律信息
T3P is a registered trademark of Archimica GmbH
警示用语：
Danger
危险分类
Eye Dam. 1 - Met. Corr. 1 - Repr. 1B - Skin Corr. 1B - Skin Sens. 1
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 2
闪点(°F)
143.6 °F
闪点(°C)
62 °C
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
H. Wissmann
Phosph. Sulfur Relat. Elem., 30, 645-645 (1986)
H. Kessler et al.
Liebigs Ann. Chem., 1-1 (1986)
M. Feigel
Journal of the American Chemical Society, 108, 181-181 (1986)
H. Wissmann et al.
Angewandte Chemie (International Edition in English), 92, 129-129 (1980)
Propylphosphonic anhydride (T3P?): an efficient reagent for the one-pot synthesis of 1, 2, 4-oxadiazoles, 1, 3, 4-oxadiazoles, and 1, 3, 4-thiadiazoles.
Augustine JK, et al.
Tetrahedron, 65(48), 9989-9996 (2009)
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