Merck
CN

850608

Sigma-Aldrich

磷酸二苯酯

99%

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别名:
Diphenyl hydrogen phosphate
线性分子式:
(C6H5O)2P(O)OH
CAS号:
分子量:
250.19
Beilstein:
1379164
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.22

检测方案

99%

形式

crystals

mp

62-66 °C (lit.)

SMILES string

OP(=O)(Oc1ccccc1)Oc2ccccc2

InChI

1S/C12H11O4P/c13-17(14,15-11-7-3-1-4-8-11)16-12-9-5-2-6-10-12/h1-10H,(H,13,14)

InChI key

ASMQGLCHMVWBQR-UHFFFAOYSA-N

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应用

磷酸二苯酯可用作可再生5-烷基δ-内酯的开环聚合(ROP)过程的有机催化剂。与碘化锌结合,其可形成异丁基乙烯基醚的活性阳离子聚合过程的新型引发系统。

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)


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Living cationic polymerization of isobutyl vinyl ether by the diphenyl phosphate/zinc iodide initiating system.
Sawamoto M, et al.
Polym. Bull., 20(5), 407-412 (1988)
Guowei Wang et al.
Environmental science & technology, 50(24), 13555-13564 (2016-12-21)
Understanding bioaccumulation and metabolism is critical for evaluating the fate and potential toxicity of compounds in vivo. We recently investigated, for the first time, the bioconcentration and tissue distribution of triphenyl phosphate (TPHP) and its main metabolites in selected tissues
Polymerization of 5-alkyl ?-lactones catalyzed by diphenyl phosphate and their sequential organocatalytic polymerization with monosubstituted epoxides.
Zhao J & Hadjichristidis N.
Polym. Chem., 6(14), 2659-2668 (2015)
Xiao Yan et al.
Chemosphere, 200, 569-575 (2018-03-06)
Urinary metabolites of phosphate flame retardants (PFRs) were determined in workers from an electronic waste (e-waste) recycling site and an incineration plant, in order to assess the PFR exposure risks of workers occupied with e-waste recycling and incineration. Bis(2-chloroethyl) phosphate
Andreia Alves et al.
Chemosphere, 168, 692-698 (2016-11-12)
In the present study, a new extraction method based on acid digestion and SPE clean-up (Oasis Wax) was developed for measuring four PFR metabolites (i.e. dibutyl phosphate (DBP), diphenyl phosphate (DPhP), bis(1,3-dichloro-2-propyl)phosphate (BDCPP) and bis(2-butoxy ethyl) phosphate (BBEP)) in hair

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