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Merck
CN

850608

Sigma-Aldrich

磷酸二苯酯

99%

别名:

磷酸氢二苯酯

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关于此项目

线性分子式:
(C6H5O)2P(O)OH
化学文摘社编号:
分子量:
250.19
Beilstein:
1379164
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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方案

99%

表单

crystals

mp

62-66 °C (lit.)

官能团

phosphate

SMILES字符串

OP(=O)(Oc1ccccc1)Oc2ccccc2

InChI

1S/C12H11O4P/c13-17(14,15-11-7-3-1-4-8-11)16-12-9-5-2-6-10-12/h1-10H,(H,13,14)

InChI key

ASMQGLCHMVWBQR-UHFFFAOYSA-N

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应用

磷酸二苯酯可用作可再生5-烷基δ-内酯的开环聚合(ROP)过程的有机催化剂。与碘化锌结合,其可形成异丁基乙烯基醚的活性阳离子聚合过程的新型引发系统。

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Living cationic polymerization of isobutyl vinyl ether by the diphenyl phosphate/zinc iodide initiating system.
Sawamoto M, et al.
Polym. Bull., 20(5), 407-412 (1988)
Guowei Wang et al.
Environmental science & technology, 50(24), 13555-13564 (2016-12-21)
Understanding bioaccumulation and metabolism is critical for evaluating the fate and potential toxicity of compounds in vivo. We recently investigated, for the first time, the bioconcentration and tissue distribution of triphenyl phosphate (TPHP) and its main metabolites in selected tissues
Polymerization of 5-alkyl ?-lactones catalyzed by diphenyl phosphate and their sequential organocatalytic polymerization with monosubstituted epoxides.
Zhao J & Hadjichristidis N.
Polym. Chem., 6(14), 2659-2668 (2015)
Michiel Bastiaensen et al.
Environment international, 146, 106147-106147 (2020-11-03)
Exposure to organophosphate flame retardants and plasticizers (PFRs) is commonly estimated by measuring biomarker concentrations in spot urine samples. However, their concentrations in urine can vary greatly over time due to short biological half-lives and variable exposure, potentially leading to
Shamil R Saitov et al.
Polymers, 11(6) (2019-05-31)
Electrical, photoelectrical, and optical properties of thin films of a new heat-resistant polyphenylquinoline synthesized using facile methods were investigated. An analysis of the obtained temperature dependences of the dark conductivity and photoconductivity indicates the hopping mechanism of conductivity over localized

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