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851450

葡醛内酯

≥99%

别名:

D-(+)-葡萄糖醛酸-3,6-内酯, D-葡糖醛酸-6,3-内酯, D-葡糖醛酸内酯, 葡糖醛酸内酯

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关于此项目

经验公式（希尔记法）:
C6H8O6
化学文摘社编号:
32449-92-6
分子量:
176.12
UNSPSC Code:
12352115
NACRES:
NA.22
PubChem Substance ID:
24888207
EC Number:
251-053-3
Beilstein/REAXYS Number:
83595
MDL number:
MFCD00135622
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Quality Level

200

assay

≥99%

form

powder

optical activity

[α]24/D +18.8°, c = 8 in H2O

mp

172-175 °C (lit.)

solubility

water: soluble 25 mg/mL, clear, colorless

SMILES string

O=C([C@@H]([C@@H](O1)[C@H](O)[C@H](O)C1=O)O)[H]

InChI

1S/C6H8O6/c7-1-2(8)5-3(9)4(10)6(11)12-5/h1-5,8-10H/t2-,3+,4-,5+/m0/s1

InChI key

UYUXSRADSPPKRZ-SKNVOMKLSA-N

General description

D-(+)-葡糖醛酸 γ-内酯（Glucourono-γ-内酯、葡糖醛酸或甘草酮）是一种碳水化合物衍生物。在动物和人体内转化为 L-抗坏血酸。其分子中含有两个五元环。对其晶体结构进行了研究。

Application

D-(+)-葡糖醛酸 γ-内酯可用于以下研究：
  • 在 2，3，4，-三 (叔丁基-二甲基硅烷）葡萄糖醛酸三氯乙酯的合成中作为起始试剂，这种酯是抗炎药 ML-3000 的 1-O-酰基葡糖苷酸的制备中必需的。
  • 光学活性吡喃葡萄糖的合成。
  • 长链烷基呋喃葡萄糖苷的合成。

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存储类别

11 - Combustible Solids

wgk

WGK 2

ppe

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SDBB6656
SDBB4637
SDBB2389
STBH1181
STBK9804

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H A Tajmir-Riahi
Biophysical chemistry, 27(3), 243-249 (1987-09-01)
The interaction of D-glucuronic and D-gluconic acids with cis- and trans-PtCl2(NH3)2 (cisplatin and transplatin) has been investigated in aqueous solution and solid complexes of the type cis-[PtL(NH3)2]L.H2O and trans-[PtL2(NH3)2]L.H2O, where L = D-glucuronate or D-gluconate anions, are isolated and characterized
J A Horne et al.
Amino acids, 20(1), 83-89 (2001-04-20)
500 ml of a glucose based "energy" drink versus a control without the active ingredients (caffeine, taurine, glucuronolactone) were given double blind to 11 sleepy participants driving an interactive real-car driving simulator. Lane drifting and a secondary task (reaction time)
Rongchun Wang et al.
Bioscience, biotechnology, and biochemistry, 74(3), 601-605 (2010-03-09)
The degradation kinetics of glucuronic acid (GlcA) under subcritical conditions from 160 to 200 degrees C was studied in a continuous tubular reactor. The formation of glucuronolactone (GlcL) during the treatment of GlcA in subcritical water was substantiated by ESI-TOF-MS
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全球贸易项目编号

货号GTIN
851450-1KG-A04061826736517
851450-100G-A04061833023570