851450
葡醛内酯
≥99%
别名:
D-(+)-葡萄糖醛酸-3,6-内酯, D-葡糖醛酸-6,3-内酯, D-葡糖醛酸内酯, 葡糖醛酸内酯
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经验公式（希尔记法）:
C6H8O6
化学文摘社编号:
分子量:
176.12
UNSPSC Code:
12352115
NACRES:
NA.22
PubChem Substance ID:
EC Number:
251-053-3
Beilstein/REAXYS Number:
83595
MDL number:
InChI key
UYUXSRADSPPKRZ-SKNVOMKLSA-N
InChI
1S/C6H8O6/c7-1-2(8)5-3(9)4(10)6(11)12-5/h1-5,8-10H/t2-,3+,4-,5+/m0/s1
SMILES string
O=C([C@@H]([C@@H](O1)[C@H](O)[C@H](O)C1=O)O)[H]
assay
≥99%
form
powder
optical activity
[α]24/D +18.8°, c = 8 in H2O
mp
172-175 °C (lit.)
solubility
water: soluble 25 mg/mL, clear, colorless
Quality Level
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General description
D-(+)-葡糖醛酸 γ-内酯（Glucourono-γ-内酯、葡糖醛酸或甘草酮）是一种碳水化合物衍生物。在动物和人体内转化为 L-抗坏血酸。其分子中含有两个五元环。对其晶体结构进行了研究。
Application
D-(+)-葡糖醛酸 γ-内酯可用于以下研究：
- 在 2，3，4，-三 (叔丁基-二甲基硅烷）葡萄糖醛酸三氯乙酯的合成中作为起始试剂，这种酯是抗炎药 ML-3000 的 1-O-酰基葡糖苷酸的制备中必需的。
- 光学活性吡喃葡萄糖的合成。
- 长链烷基呋喃葡萄糖苷的合成。
存储类别
11 - Combustible Solids
wgk
WGK 2
ppe
Eyeshields, Gloves, type N95 (US)
J M Hsu et al.
The Journal of nutrition, 111(1), 141-145 (1981-01-01)
The effect of feeding 0.25% ethionine for 3-10 weeks to male and female rats on urinary and tissue ascorbate contents were studied. The concentrations of ascorbic acid in the urine, blood, liver and adrenals were significantly reduced in the rats
H A Tajmir-Riahi
Biophysical chemistry, 27(3), 243-249 (1987-09-01)
The interaction of D-glucuronic and D-gluconic acids with cis- and trans-PtCl2(NH3)2 (cisplatin and transplatin) has been investigated in aqueous solution and solid complexes of the type cis-[PtL(NH3)2]L.H2O and trans-[PtL2(NH3)2]L.H2O, where L = D-glucuronate or D-gluconate anions, are isolated and characterized
Synthesis and biological identification of the acyl glucuronide of the antiinflammatory drug ML-3000.
Kirschning A, et al.
Bioorganic & Medicinal Chemistry Letters, 7(7), 903-906 (1997)
Matthew I Worthley et al.
The American journal of medicine, 123(2), 184-187 (2010-01-28)
Energy drink consumption has been anecdotally linked with sudden cardiac death and, more recently, myocardial infarction. As myocardial infarction is strongly associated with both platelet and endothelial dysfunction, we tested the hypothesis that energy drink consumption alters platelet and endothelial
Chemical & Pharmaceutical Bulletin, 41, 1197-1197 (1993)
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