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Merck
CN

857297

D-(+)-核糖酸 γ-内酯

97%

别名:

D-(+)-核糖酸-1,4-内酯

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关于此项目

经验公式(希尔记法):
C5H8O5
化学文摘社编号:
分子量:
148.11
UNSPSC Code:
12352202
NACRES:
NA.22
PubChem Substance ID:
EC Number:
226-256-5
Beilstein/REAXYS Number:
82057
MDL number:
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产品名称

D-(+)-核糖酸 γ-内酯, 97%

InChI key

CUOKHACJLGPRHD-BXXZVTAOSA-N

InChI

1S/C5H8O5/c6-1-2-3(7)4(8)5(9)10-2/h2-4,6-8H,1H2/t2-,3-,4-/m1/s1

SMILES string

OC[C@H]1OC(=O)[C@H](O)[C@@H]1O

assay

97%

form

crystals

optical activity

[α]24/D +18°, c = 1 in H2O

mp

85-87 °C (lit.)

Quality Level

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Application

用于手性非环系、环戊烯酮类和氧杂双环体系的重要结构单元。还用于研究非线性光学材料。

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Aldrichimica Acta, 22, 49-49 (1989)
Chemistry of Materials, 5, 802-802 (1993)
Jan-Moritz Sutter et al.
FEMS microbiology letters, 364(13) (2017-09-01)
Haloferax volcanii degrades the pentoses D-xylose and L-arabinose via an oxidative pathway to α-ketoglutarate as an intermediate. The initial dehydrogenases of the pathway, D-xylose dehydrogenase (XDH) and L-arabinose dehydrogenase (L-AraDH) catalyze the NADP+ dependent D-xylose and L-arabinose oxidation. It is
High resolution gas chromatographic/real-time high resolution mass spectrometric identification of organic acids in human urine.
S Lewis et al.
Analytical chemistry, 51(8), 1275-1285 (1979-07-01)
P C Raveendranath et al.
Carbohydrate research, 253, 207-223 (1994-02-03)
A series of 3-C-alkyl- (and 3-C-phenyl-) 2,3-dideoxy-D-erythro-pentono-1,4-lactones, compounds which are important in the synthesis of modified nucleosides and antibiotic sugars, were synthesized from D-ribonolactone. By a route that proceeded via 5-O-protected D-ribonolactone, 5-O-protected 2,3-dideoxy-D-glycero-pent-2-enono-1,4-lactones were synthesized and reacted with R2CuLi

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