857297
D-(+)-核糖酸 γ-内酯
97%
别名:
D-(+)-核糖酸-1,4-内酯
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关于此项目
经验公式（希尔记法）:
C5H8O5
化学文摘社编号:
分子量:
148.11
UNSPSC Code:
12352202
NACRES:
NA.22
PubChem Substance ID:
EC Number:
226-256-5
Beilstein/REAXYS Number:
82057
MDL number:
InChI key
CUOKHACJLGPRHD-BXXZVTAOSA-N
InChI
1S/C5H8O5/c6-1-2-3(7)4(8)5(9)10-2/h2-4,6-8H,1H2/t2-,3-,4-/m1/s1
SMILES string
OC[C@H]1OC(=O)[C@H](O)[C@@H]1O
assay
97%
form
crystals
optical activity
[α]24/D +18°, c = 1 in H2O
mp
85-87 °C (lit.)
Quality Level
Application
用于手性非环系、环戊烯酮类和氧杂双环体系的重要结构单元。还用于研究非线性光学材料。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Chemistry of Materials, 5, 802-802 (1993)
Aldrichimica Acta, 22, 49-49 (1989)
Jan-Moritz Sutter et al.
FEMS microbiology letters, 364(13) (2017-09-01)
Haloferax volcanii degrades the pentoses D-xylose and L-arabinose via an oxidative pathway to α-ketoglutarate as an intermediate. The initial dehydrogenases of the pathway, D-xylose dehydrogenase (XDH) and L-arabinose dehydrogenase (L-AraDH) catalyze the NADP+ dependent D-xylose and L-arabinose oxidation. It is
Virginie Faure et al.
Biochemical and biophysical research communications, 328(4), 1188-1195 (2005-02-15)
Free radical attack on the sugar-phosphate backbone generates oxidized apurinic/apyrimidinic (AP) residues in DNA. 2'-deoxyribonolactone (dL) is a C1'-oxidized AP site damage generated by UV and gamma-irradiation, and certain anticancer drugs. If not repaired dL produces G-->A transitions in Escherichia
B A Horenstein et al.
Biochemistry, 32(28), 7089-7097 (1993-07-20)
A new approach to understanding transition-state structure is presented which involves the sequential application of experimental and computational methods. A family of experimentally determined kinetic isotope effects is fit simultaneously in a vibrational analysis to provide a geometric model of
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