四丁基醋酸铵

Name: 四丁基醋酸铵
Brand: ALDRICH

≥90% (T), powder, technical grade

别名:

TBAAc

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About This Item

线性分子式:

(CH₃CH₂CH₂CH₂)₄N(OCOCH₃)

CAS Number:

10534-59-5

分子量:

301.51

Beilstein:

3599376

EC 号:

234-101-8

MDL编号:

MFCD00043208

UNSPSC代码:

12352116

PubChem化学物质编号:

57653198

NACRES:

NA.22

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Product Name

四丁基醋酸铵, technical, ≥90% (T)

等级

technical

质量水平

100

方案

≥90% (T)

表单

powder

mp

95-98 °C (lit.)

SMILES字符串

CC([O-])=O.CCCC[N+](CCCC)(CCCC)CCCC

InChI

1S/C16H36N.C2H4O2/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-2(3)4/h5-16H2,1-4H3;1H3,(H,3,4)/q+1;/p-1

InChI key

MCZDHTKJGDCTAE-UHFFFAOYSA-M

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一般描述

Tetrabutylammonium acetate is an effective alternative for sodium acetate (NaOAc) due to its good solubility in organic solvents.

应用

Tetrabutylammonium acetate (TBAAc) is a good source of nucleophilic acetate ion for SN₂ substitution reactions. It is commonly used to displace sulfonates and allylic halides to get corresponding acetates. Additionally, TBAAc can also be used as a mild, soluble base in Sonogashira reaction and Heck arylation.