86885
四丁基高氯酸铵
≥95.0% (T)
别名:
高氯酸四丁基铵（TBAP）
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关于此项目
线性分子式:
(CH3CH2CH2CH2)4N(ClO4)
化学文摘社编号:
分子量:
341.91
UNSPSC Code:
12352116
NACRES:
NA.22
PubChem Substance ID:
EC Number:
217-655-5
Beilstein/REAXYS Number:
3579274
MDL number:
产品名称
四丁基高氯酸铵, ≥95.0% (T)
InChI key
KBLZDCFTQSIIOH-UHFFFAOYSA-M
InChI
1S/C16H36N.ClHO4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;(H,2,3,4,5)/q+1;/p-1
SMILES string
[O-]Cl(=O)(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC
assay
≥95.0% (T)
form
powder
reaction suitability
reagent type: oxidant
functional group
amine
Quality Level
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Application
四丁基高氯酸铵是一种四烷基铵盐，可用于相转移催化。
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
5.1B - Oxidizing hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
ESCA studies of phase-transfer catalysts in solution: ion pairing and surface activity
Moberg R, et al.
Journal of the American Chemical Society, 113(10), 3663-3667 (1991)
David Balcells et al.
Dalton transactions (Cambridge, England : 2003), (30)(30), 5989-6000 (2009-07-23)
Experimental studies have shown that the C-H oxidation of Ibuprofen and methylcyclohexane acetic acid can be carried out with high selectivities using [(terpy')Mn(OH(2))(mu-O)(2)Mn(OH(2))(terpy')](3+) as catalyst, where terpy' is a terpyridine ligand functionalized with a phenylene linker and a Kemp's triacid
Atanu Jana et al.
Dalton transactions (Cambridge, England : 2003), 44(1), 359-367 (2014-11-11)
A novel electron rich, tetrathiafulvalene fused zinc porphyrin, (TTF)4PZn, has been newly synthesized and characterized using spectral and electrochemical methods. In spite of the presence of eight t-butyl groups, (TTF)4PZn exhibited appreciable aggregation in solution. Scanning electron microscopic (SEM) imaging
Shohei Sakashita et al.
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Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions of tetrabutylammonium 2-pyridyltriolborate salts with various aryl (heteroaryl) chlorides can produce the corresponding desired coupling products with good to excellent yields. These tetrabutylammonium salts are more reactive than the corresponding lithium salts. The coupling reactions with
Kosei Sugahara et al.
Chemical communications (Cambridge, England), 48(67), 8422-8424 (2012-07-14)
A tetra-n-butylammonium (TBA) salt of a γ-Keggin -6-charged germanodecatungstate, [γ-H(2)GeW(10)O(36)](6-) (I), could act as an efficient homogeneous catalyst for Knoevenagel condensation of active methylene compounds with carbonyl compounds.
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