87189
1-十四烯
≥97.0% (GC)
别名:
1-Butadecene, n-Tetradec-1-ene, alpha-Tetradecene
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关于此项目
线性分子式:
CH3(CH2)11CH=CH2
化学文摘社编号:
分子量:
196.37
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
214-306-9
Beilstein/REAXYS Number:
1701156
MDL number:
产品名称
1-十四烯, ≥97.0% (GC)
InChI key
HFDVRLIODXPAHB-UHFFFAOYSA-N
InChI
1S/C14H28/c1-3-5-7-9-11-13-14-12-10-8-6-4-2/h3H,1,4-14H2,2H3
SMILES string
CCCCCCCCCCCCC=C
vapor density
6.8 (vs air)
assay
≥97.0% (GC)
form
liquid
autoignition temp.
455 °F
refractive index
n20/D 1.436 (lit.)
n20/D 1.436
bp
251 °C (lit.)
mp
−13-−11 °C (lit.)
density
0.775 g/mL at 25 °C (lit.)
functional group
allyl
Quality Level
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Application
1-Tetradecene can be used as a reactant to synthesize:
It can also be used as a monomer unit to synthesize high molecular weight polymer [poly(1- tetradecene)] by titanium complex catalyzed polymerization reaction.
- 2-Tetradecanone via PdCl2/CrO3 catalyzed oxidation reaction.
- (E)-ethyl pentadec-2-enoate, which is used as a key intermediate in the diastereoselective synthesis of (+)-nephrosterinic acid and (+)-protolichesterinic acid via Johnson-Claisen rearrangement.
It can also be used as a monomer unit to synthesize high molecular weight polymer [poly(1- tetradecene)] by titanium complex catalyzed polymerization reaction.
signalword
Danger
hcodes
Hazard Classifications
Asp. Tox. 1
supp_hazards
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
230.0 °F
flash_point_c
110 °C
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Diastereoselective synthesis of (+)-nephrosterinic acid and (+)-protolichesterinic acid
Fernandes RA, et al.
Tetrahedron Asymmetry, 23(1), 60-66 (2012)
Synthesis of ultrahigh molecular weight polymers with low PDIs by polymerizations of 1-decene, 1-dodecene, and 1-tetradecene by Cp* TiMe2 (O-2, 6-iPr2C6H3)-borate catalyst
Nomura K, et al.
Molecules (Basel), 24(8), 1634-1634 (2019)
Synthesis of methyl ketones from terminal olefins using PdCl2/CrO3 system mimicking the Wacker process
Fernandes RA and Bethi V
Tetrahedron, 70(32), 4760-4767 (2014)
Marta Krasny et al.
Cell and tissue banking, 16(4), 631-638 (2015-07-15)
Increasingly dental surgeons face the challenge of reconstruction of the height and/or thickness of the alveolar ridge as more and more patients wish to have permanent restoration of their dental defects based on intraosseous implants. Evaluation of human allogeneic bone
Lucas A Lane et al.
The journal of physical chemistry. B, 118(49), 14140-14147 (2014-08-27)
Quantum dots (QDs) offer distinct advantages over organic dyes and fluorescent proteins for biological imaging applications because of their brightness, photostability, and tunability. However, a major limitation is that single QDs emit fluorescent light in an intermittent on-and-off fashion called
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