Merck
CN
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文件

87189

Sigma-Aldrich

1-十四烯

≥97.0% (GC)

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别名:
1-Butadecene, n-Tetradec-1-ene, alpha-Tetradecene
线性分子式:
CH3(CH2)11CH=CH2
CAS号:
1120-36-1
分子量:
196.37
Beilstein:
1701156
EC 号:
214-306-9
MDL编号:
MFCD00008981
PubChem化学物质编号:
57653175
NACRES:
NA.22

蒸汽密度

6.8 (vs air)

检测方案

≥97.0% (GC)

形式

liquid

自燃温度

455 °F

折射率

n20/D 1.436 (lit.)
n20/D 1.436

bp

251 °C (lit.)

mp

−13-−11 °C (lit.)

密度

0.775 g/mL at 25 °C (lit.)

SMILES string

CCCCCCCCCCCCC=C

InChI

1S/C14H28/c1-3-5-7-9-11-13-14-12-10-8-6-4-2/h3H,1,4-14H2,2H3

InChI key

HFDVRLIODXPAHB-UHFFFAOYSA-N

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相关类别

应用

1-Tetradecene can be used as a reactant to synthesize:
  • 2-Tetradecanone via PdCl2/CrO3 catalyzed oxidation reaction.
  • (E)-ethyl pentadec-2-enoate, which is used as a key intermediate in the diastereoselective synthesis of (+)-nephrosterinic acid and (+)-protolichesterinic acid via Johnson-Claisen rearrangement.

It can also be used as a monomer unit to synthesize high molecular weight polymer [poly(1- tetradecene)] by titanium complex catalyzed polymerization reaction.

象形图

Health hazard
GHS08

警示用语：

Danger

危险声明

H304

危险分类

Asp. Tox. 1

补充剂危害

EUH066

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

230.0 °F

闪点(°C)

110 °C

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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