88755
(R)-1-[(SP)-2-(二叔丁基膦)二茂铁基]乙基双(2-甲基苯基)膦
97%
别名:
(1R)-1-[双(1,1-二甲基乙基)膦]-2-[(1R)-1-[双(2-甲基苯基)膦]乙基]二茂铁（符合 CAS 标准）, Josiphos SL-J505-1
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选择尺寸
关于此项目
经验公式（希尔记法）:
C34H44FeP2
化学文摘社编号:
分子量:
570.51
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
InChI
1S/C29H39P2.C5H5.Fe/c1-21-15-10-12-18-25(21)30(26-19-13-11-16-22(26)2)23(3)24-17-14-20-27(24)31(28(4,5)6)29(7,8)9;1-2-4-5-3-1;/h10-20,23H,1-9H3;1-5H;/t23-;;/m1../s1
SMILES string
[Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2P(C(C)(C)C)C(C)(C)C)P(c3ccccc3C)c4ccccc4C
InChI key
DSZYQALCGVODLB-MQWQBNKOSA-N
assay
97%
form
powder
optical purity
ee: ≥99%
functional group
phosphine
Quality Level
General description
与 Solvias AG 联合销售
(R)-1-[(SP)-2-(Di-tert-butylphosphino)ferrocenyl]ethylbis(2-methylphenyl)phosphine is a chiral ferrocenyl diphosphine ligand.
Application
It may be used as ligand to prepare 4,7-amino-1,10-phenanthroline containing N- and O- containing macrocyclic ligands via palladium catalyzed amination reactions.
Packaging
Bottomless glass bottle. Contents are inside inserted fused cone.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Ditopic Macrocyclic Receptors with a 4,7-Diamino-1,10-phenanthroline Fragment for Multimodal Detection of Toxic Metal Ions.
Abel AS, et al.
ChemPlusChem, 81(1), 35-39 (2016)
Privileged ligands
Aldrich Chemfiles, 6(8), 12-12 null
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