产品名称
Cyanomethyl (3,5-Dimethyl-1H-pyrazole)-carbodithioate, 95%
InChI
1S/C8H9N3S2/c1-6-5-7(2)11(10-6)8(12)13-4-3-9/h5H,4H2,1-2H3
SMILES string
CC1=NN(C(SCC#N)=S)C(C)=C1
InChI key
OMTFYPHYESIDFH-UHFFFAOYSA-N
assay
95%
form
powder
storage condition
protect from light
mp
104-109 °C
Quality Level
Application
A stable, dithiocarbamate chain transfer agent (CTA), also referred to as a RAFT agent, that can control chain growth in free radical polymerization, producing polymers with well-defined molecular weights, and low polydispersities. Cyanomethyl (3,5-Dimethyl-1H-pyrazole)-carbodithioate can be used to control homo-polymerisation and co-polymerisation of acrylic acid, acrylates, acrylamides, and styrenes (2o MAMs), and LAMs such as vinyl acetate and N-vinylpyrrolidinone. It can be used to make MAM-LAM block copolymers. It is soluble in organic media.
Legal Information
Sold for research purposes only: See sigma-aldrich.com/raftlicense
Patents: WO98/01478, WO99/311444.
Patents: WO98/01478, WO99/311444.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Dithiocarbamate RAFT agents with broad applicability ? the 3,5-dimethyl-1H-pyrazole-1-carbodithioates.
Gardiner J, et al.
Polym. Chem., 7, 481-492 (2016)
Beth Marbois et al.
The Journal of biological chemistry, 285(36), 27827-27838 (2010-07-02)
Coenzyme Q (ubiquinone or Q) is a crucial mitochondrial lipid required for respiratory electron transport in eukaryotes. 4-Hydroxybenozoate (4HB) is an aromatic ring precursor that forms the benzoquinone ring of Q and is used extensively to examine Q biosynthesis. However
商品
The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.
Low-cost, high-purity RAFT Agents are vital for industrial RAFT polymerization. We supply effective agents for this technology.
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