900624
Di-t-butyl oxaziridine
≥95%
别名:
Kurti oxaziridine
登录 查看组织和合同定价。
选择尺寸
关于此项目
经验公式（希尔记法）:
C9H19NO
化学文摘社编号:
分子量:
157.25
MDL number:
UNSPSC Code:
12352000
NACRES:
NA.22
InChI
1S/C9H19NO/c1-7(2,3)9(10-11-9)8(4,5)6/h10H,1-6H3
InChI key
BEGIYSAPGHHUSW-UHFFFAOYSA-N
SMILES string
CC(C)(C)C1(NO1)C(C)(C)C
assay
≥95%
form
liquid
availability
available only in USA
refractive index
n/D 1.4453
density
0.90 g/mL
storage temp.
2-8°C
Quality Level
Application
This oxaziridine has been used in synthetic methods for amination, heteroatom transfer, and C-H functionalization. Recently, the lab of Laszlo Kurti demonstrated its application for direct electrophilic primary and secondary amination of arylmetals in the presence of Cu(I) salts -- void of precious metal catalysts, ligands, protecting groups, or directing groups.
signalword
Danger
hcodes
Hazard Classifications
Self-react. C
存储类别
5.2 - Organic peroxides and self-reacting hazardous materials
wgk
WGK 3
flash_point_f
143.6 °F
flash_point_c
62 °C
法规信息
新产品
此项目有
Zhe Zhou et al.
Journal of the American Chemical Society, 139(1), 115-118 (2016-12-23)
Herein we disclose a novel method for the facile transfer of primary (-NH2) and secondary amino groups (-NHR) to heteroaryl- as well as arylcuprates at low temperature without the need for precious metal catalysts, ligands, excess reagents, protecting and/or directing
Yan Xu et al.
Nature chemistry, 7(10), 829-834 (2015-09-24)
Site-selective C-H functionalization has emerged as an attractive tool for derivatizing complex synthetic intermediates, but its use for late-stage diversification is limited by the functional groups that can be introduced, especially at unactivated sp(3)-hybridized positions. To overcome this, we introduce
Hongyin Gao et al.
Nature chemistry, 9(7), 681-688 (2017-06-24)
Arylmetals are highly valuable carbon nucleophiles that are readily and inexpensively prepared from aryl halides or arenes and widely used on both laboratory and industrial scales to react directly with a wide range of electrophiles. Although C-C bond formation has
Synthesis of Alkoxylamines by Alkoxide Amination with 3,3'-Di-tert-butyloxaziridine.
Ingrid C. Choong et al.
The Journal of organic chemistry, 64(18), 6528-6529 (2001-10-25)
相关内容
Amines and their derivatives are ubiquitous substances since they make up the overwhelming majority of drug molecules, agrochemicals as well as many compounds that are produced by plants and living organisms (i.e., natural products).
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持