所有图片(3)

文件

901111

Phenox O-PC^™ A0202

Name: Phenox O-PC<SUP>™</SUP> A0202
Brand: ALDRICH

New Iridium, ≥97%

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所有图片(3)

别名:

3,7-二（[1,1'-联苯]-4-基）-10-（萘-1-基）-10H-吩恶嗪, Miyake 有机光电催化剂, PhenO_1Naph_Biph

经验公式（希尔记法）:

C₄₆H₃₁NO

CAS号:

1987900-95-7

分子量:

613.74

质量水平

100

检测方案

≥97%

形式

powder or crystals

反应适用性

reagent type: catalyst
reaction type: Photocatalysis

mp

171 °C

光触媒活化

400 nm

SMILES字符串

C1(C=CC(C2=CC=C(C3=CC=CC=C3)C=C2)=C4)=C4OC(C=C(C5=CC=C(C6=CC=CC=C6)C=C5)C=C7)=C7N1C8=C(C=CC=C9)C9=CC=C8

应用

该二氢吩嗪基有机光氧化还原催化剂（除二氢吩嗪催化剂901112外）被设计为一种强激发态还原剂，并具有高级的光物理和电化学性能，使其能够用作钌或铱基光氧化还原催化剂的可持续替代品。例如，在光氧化还原催化的原子转移自由基聚合（ATRP）的应用中，二氢吩嗪和吩恶嗪衍生物被证明可替代钌或铱配合物，以控制聚合物的合成和小分子转化，例如三氟甲基化、原子转移自由基的加成和双镍/光氧化还原催化的CN和CS交叉偶联。在与Miyake 研究小组的合作中，采用了二氢吩嗪和苯恶嗪基有机光氧化还原催化剂。

产品可以和我们的光反应器系列一起使用：包括Penn PhD（Z744035）& SynLED 2.0 （Z744080）

其他说明

强烈还原可见光有机光还原催化剂可持续替代贵金属

可见光驱动的有机催化原子转移自由基聚合

以 N -芳基吩恶嗪为光还原剂的有机催化原子转移自由基聚合

N, N -二芳二氢吩嗪光还原催化剂中的分子内电荷转移和离子对

法律信息

专利申请PCT/US2016/058245。与New Iridium Inc.合作出售。如需大于25克的订单，请通过chern@newiridium.com与New Iridium联系，或访问https://www.newiridium.com。

Phenox O-PC is a trademark of New Iridium LLC

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

分析证书(COA)

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示例

T1503

货号

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25G

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705578-5MG-PW

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MMYOMAG-74K-13

1000309185

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索取COA

Organocatalyzed Atom Transfer Radical Polymerization Using N-Aryl Phenoxazines as Photoredox Catalysts.

Pearson, et al.

Journal of the American Chemical Society, 138, 11399-11407 (2017)

Organocatalyzed atom transfer radical polymerization driven by visible light.

Jordan C Theriot et al.

Science (New York, N.Y.), 352(6289), 1082-1086 (2016-04-02)

Atom transfer radical polymerization (ATRP) has become one of the most implemented methods for polymer synthesis, owing to impressive control over polymer composition and associated properties. However, contamination of the polymer by the metal catalyst remains a major limitation. Organic

Strongly Reducing, Visible-Light Organic Photoredox Catalysts as Sustainable Alternatives to Precious Metals.

Ya Du et al.

Chemistry (Weinheim an der Bergstrasse, Germany), 23(46), 10962-10968 (2017-06-28)

Photoredox catalysis is a versatile approach for the construction of challenging covalent bonds under mild reaction conditions, commonly using photoredox catalysts (PCs) derived from precious metals. As such, there is need to develop organic analogues as sustainable replacements. Although several

Intramolecular Charge Transfer and Ion Pairing in N,N-Diaryl Dihydrophenazine Photoredox Catalysts for Efficient Organocatalyzed Atom Transfer Radical Polymerization.

Chern-Hooi Lim et al.

Journal of the American Chemical Society, 139(1), 348-355 (2016-12-16)

Photoexcited intramolecular charge transfer (CT) states in N,N-diaryl dihydrophenazine photoredox catalysts are accessed through catalyst design and investigated through combined experimental studies and density functional theory (DFT) calculations. These CT states are reminiscent of the metal to ligand charge transfer

Organocatalyzed Atom Transfer Radical Polymerization Using N-Aryl Phenoxazines as Photoredox Catalysts.

Ryan M Pearson et al.

Journal of the American Chemical Society, 138(35), 11399-11407 (2016-08-25)

N-Aryl phenoxazines have been synthesized and introduced as strongly reducing metal-free photoredox catalysts in organocatalyzed atom transfer radical polymerization for the synthesis of well-defined polymers. Experiments confirmed quantum chemical predictions that, like their dihydrophenazine analogs, the photoexcited states of phenoxazine

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商品

Reducing Organic Photoredox Catalysts for Visible Light-Driven Polymer and Small Molecule Synthesis

Photoredox catalysis is a powerful synthetic methodology to form challenging covalent bonds using light irradiation. It is effective for light-driven polymer and small molecule synthesis.

文件

Phenox O-PC™ A0202