901126
trans-Bis(tribenzylphosphine)(2-methylphenyl)nickel(II) chloride
95%
别名:
trans-(PBn3)2Ni(o-tolyl)Cl
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关于此项目
Assay:
95%
Form:
powder or solid
assay
95%
form
powder or solid
reaction suitability
reaction type: Cross Couplings, reagent type: catalyst
mp
200-205 °C
SMILES string
Cl[Ni](C1=C(C)C=CC=C1)(P(CC2=CC=CC=C2)(CC3=CC=CC=C3)CC4=CC=CC=C4)P(CC5=CC=CC=C5)(CC6=CC=CC=C6)CC7=CC=CC=C7
Application
The following Ni-complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)2, however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)2. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)2.
Other Notes
Legal Information
Patent application PCT/US2014/064565. Sold under license from the Massachusetts Institute of Technology.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable