trans-Bis(tribenzylphosphine)(2-methylphenyl)nickel(II) chloride

Name: <I>trans</I>-Bis(tribenzylphosphine)(2-methylphenyl)nickel(II) chloride
Brand: ALDRICH

95%

别名:

trans-(PBn₃)₂Ni(o-tolyl)Cl

登录查看组织和合同定价。

选择尺寸

关于此项目

经验公式（希尔记法）:

C₄₉H₄₉ClNiP₂

化学文摘社编号:

1594112-87-4

分子量:

794.01

UNSPSC Code:

12352200

主要文件

查看所有文档

技术服务

需要帮助？我们经验丰富的科学家团队随时乐意为您服务。

让我们为您提供帮助

技术服务

需要帮助？我们经验丰富的科学家团队随时乐意为您服务。

让我们为您提供帮助

产品名称

trans-Bis(tribenzylphosphine)(2-methylphenyl)nickel(II) chloride, 95%

SMILES string

Cl[Ni](C1=C(C)C=CC=C1)(P(CC2=CC=CC=C2)(CC3=CC=CC=C3)CC4=CC=CC=C4)P(CC5=CC=CC=C5)(CC6=CC=CC=C6)CC7=CC=CC=C7

assay

95%

form

powder or solid

reaction suitability

reaction type: Cross Couplings
reagent type: catalyst

mp

200-205 °C

Application

The following Ni-complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)_2, however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)₂. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)₂.

Legal Information

Patent application PCT/US2014/064565. Sold under license from the Massachusetts Institute of Technology.

Other Notes

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

新产品

此项目有

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

MKCF3675

没有发现合适的版本？

如果您需要特殊版本，可通过批号或批次号查找具体证书。

搜索COA

已有该产品？

在文件库中查找您最近购买产品的文档。

访问文档库

Recent advances in homogeneous nickel catalysis.

Tasker S Z, et al.

Nature, 509(7500), 299-299 (2014)

Recent advances in homogeneous nickel catalysis.

Sarah Z Tasker et al.

Nature, 509(7500), 299-309 (2014-05-16)

Tremendous advances have been made in nickel catalysis over the past decade. Several key properties of nickel, such as facile oxidative addition and ready access to multiple oxidation states, have allowed the development of a broad range of innovative reactions.

商品

Jamison Nickel (II) Precatalysts

The Jamison group has developed a library of bench-stable phosphine-containing nickel(II) precatalysts that are converted into active catalysts in situ.

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

trans-Bis(tribenzylphosphine)(2-methylphenyl)nickel(II) chloride

95%

选择尺寸

关于此项目

主要文件

属性

产品名称

SMILES string

assay

form

reaction suitability

mp

说明

Application

Legal Information

Other Notes

安全信息

存储类别

wgk

flash_point_f

flash_point_c

法规信息

文件

分析证书(COA)

已有该产品？

同行评审论文

技术文章和实验方案

商品

相关内容

技术服务