901166
cis-[2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl](2-methylphenyl)nickel(II) chloride
powder or solid
别名:
cis-((S)-BINAP)Ni(o-tolyl)Cl
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关于此项目
经验公式（希尔记法）:
C51H39ClNiP2
化学文摘社编号:
分子量:
807.95
MDL number:
UNSPSC Code:
12161600
NACRES:
NA.22
产品名称
cis-[2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl](2-methylphenyl)nickel(II) chloride,
form
powder or solid
Quality Segment
reaction suitability
core: nickel, reaction type: Cross Couplings, reagent type: catalyst
mp
>300 °C
SMILES string
Cl[Ni]1(P(C2=C([H])C([H])=C([H])C([H])=C2[H])(C3=C([H])C([H])=C([H])C([H])=C3[H])C(C([H])=C4[H])=[C@@]([C@@]5=C(P1(C6=C([H])C([H])=C([H])C([H])=C6[H])C7=C([H])C([H])=C([H])C([H])=C7[H])C([H])=C([H])C8=C5C([H])=C([H])C([H])=C8[H])C9=C4C([H])=C([H])C([H])=C
Application
The following Ni-complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)2, however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)2. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)2.
Other Notes
Legal Information
Patent application PCT/US2014/064565. Sold under license from the Massachusetts Institute of Technology.
存储类别
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable