assay
≥95%
form
powder or crystals
reaction suitability
reagent type: catalyst, reagent type: ligand
reaction type: C-H Activation
mp
142 °C
Application
(S)-Ph-quinox is a chiral dinitrogen ligand which is used in the iridium-catalyzed enantioselective borylation and silylation of aromatic C-H bonds, in addition to the enantioselective palladium-catalyzed diamination of alkenes. It can also be used in the aza-Wacker-type cyclization reaction of the olefinic tosylamides with molecular oxygen.
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
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商品
QuinoxP*: Air-Stable and Highly Efficient and Productive Chiral Ligands
Pd-catalyzed asymmetric aza-Wacker-type cyclization reaction of olefinic tosylamides.
Jiang F, et al.
Tetrahedron Letters, 51(39), 5124-5126 (2010)
Enantioselective Borylation of Aromatic C? H Bonds with Chiral Dinitrogen Ligands.
Su B, et al.
Angewandte Chemie (International Edition in English), 56(25), 7205-7208 (2017)
A Chiral Nitrogen Ligand for Enantioselective, Iridium?Catalyzed Silylation of Aromatic C? H Bonds.
Su B, et al.
Angewandte Chemie (Weinheim an der Bergstrasse, Germany), 129(4), 1112-1116 (2017)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 901216-250MG | 04061835505319 |