质量水平
方案
≥95%
表单
powder or chunks
mp
145-147 °C
官能团
phenyl
thioether
储存温度
2-8°C
SMILES字符串
C12=CC=CC=C1SC3=N[C@@H](C4=CC=CC=C4)CCN23
InChI
1S/C16H14N2S/c1-2-6-12(7-3-1)13-10-11-18-14-8-4-5-9-15(14)19-16(18)17-13/h1-9,13H,10-11H2/t13-/m1/s1
InChI key
ZMYZJAQMQBHNLH-CYBMUJFWSA-N
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应用
This chiral isothiourea homobenzotetramisole ((R)-HBTM) developed by the Birman lab is an organocatalyst that has been used for kinetic resolution, determination of absolute configuration, and nucleophile-catalysed, Michael–aldol-b-lactonization (NCMAL). This same product was previously listed as L511730, and the complementary (S)-HBTM organocatalyst (900542) is also available.
其他说明
Technology Spotlight: Homobenzotetramisole (HBTM): A General Organocatalyst for Asymmetric Acylations
[1] Determination of the Absolute Configuration β-Chiral Primary Alcohols Using the Competing Enantioselective Conversion Method
[2] Asymmetric Catalytic Synthesis of Thiochromenes via an Acyl Transfer-Initiated Cascade
[3] Rapid assembly of complex cyclopentanes employing chiral, α, β-unsaturated acylammonium intermediates
[4] Determination of Absolute Configuration Using Kinetic Resolution Catalysts
[5] Kinetic Resolution of Secondary Alcohols Using Amidine-Based Catalysts
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
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