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About This Item
线性分子式:
(C2H5)3P
CAS Number:
分子量:
118.16
Beilstein:
969170
MDL编号:
UNSPSC代码:
12352128
NACRES:
NA.22
Product Name
三乙基膦 溶液, 1.0 M in 2-methyltetrahydrofuran
表单
liquid
质量水平
反应适用性
reagent type: ligand
reaction type: Arylations
浓度
1.0 M in 2-methyltetrahydrofuran
密度
0.843 g/mL
官能团
phosphine
SMILES字符串
CCP(CC)CC
InChI
1S/C6H15P/c1-4-7(5-2)6-3/h4-6H2,1-3H3
InChI key
RXJKFRMDXUJTEX-UHFFFAOYSA-N
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应用
Catalyst for:
- Regioselective formation of alcohols from hydrocarbonylation of alkenes
- Bronsted acid-assisted synthesis of dihydropyrones from aromatic aldehydes and allenoates
- Silaboration of enynes
- Conversion of phenylacetic acids to phenylacetonitriles of benzonitriles
- Thermal decomposition of platinum and palladium naphthalenediyl
- Asymmetrical Morita-Baylis-Hillman reaction
Offered as the 2-methyltetrahydrofuran solution for more convenient handling, triethylphosphine is a valuable ligand for:
- Regioselective formation of alcohols from hydrocarbonylation of alkenes.
- Bronsted acid-assisted synthesis of dihydropyrones from aromatic aldehydes and allenoates.
- Silaboration of enynes.
- Conversion of phenylacetic acids to phenylacetonitriles of benzonitriles.
- Thermal decomposition of platinum and palladium naphthalenediyl.
- Asymmetrical Morita-Baylis-Hillman reaction.
警示用语:
Danger
危险分类
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B
补充剂危害
储存分类代码
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 3
闪点(°F)
8.6 °F
闪点(°C)
-13 °C
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