901464
2,2′-Bi-1,3,2-dioxaborinane
≥95%
别名:
B2(pro)2, Propanediol diboron
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关于此项目
经验公式（希尔记法）:
C6H12B2O4
化学文摘社编号:
分子量:
169.78
UNSPSC Code:
12352200
NACRES:
NA.22
MDL number:
Assay:
≥95%
Form:
powder or crystals
产品名称
2,2′-Bi-1,3,2-dioxaborinane, ≥95%
SMILES string
B2(OCCCO2)B1OCCCO1
InChI
1S/C6H12B2O4/c1-3-9-7(10-4-1)8-11-5-2-6-12-8/h1-6H2
InChI key
FOGDFVUQHQEIPV-UHFFFAOYSA-N
assay
≥95%
form
powder or crystals
greener alternative product characteristics
Catalysis
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Greener Alternative Product
mp
156 °C
greener alternative category
storage temp.
−20°C
Quality Level
Application
As reported by the laboratory of James Morken, B2(pro)2 is an effective reagent for enantioselective diboration of alkenes when used in conjunction with the carbohydrate-derived catalysts TBS-DHG (901235) or DHR (901237). Useful for synthesis of other boron-containing molecules.
General description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced to increase catalytic efficiency. Click here for more information.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
此项目有
Lu Yan et al.
Journal of the American Chemical Society, 140(10), 3663-3673 (2018-02-15)
A mechanistic investigation of the carbohydrate/DBU cocatalyzed enantioselective diboration of alkenes is presented. These studies provide an understanding of the origin of stereoselectivity and also reveal a strategy for enhancing reactivity and broadening the substrate scope.
相关内容
Chiral organoboronic esters are well known as versatile intermediates for chemical synthesis. Not only are these compounds stable under a variety of reaction conditions, they are generally non-toxic and can be transformed with minimal generation of hazardous waste.
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