904694
Ir(p-CF3-ppy)3
≥95%, powder or crystals
别名:
三[2-(2-吡啶-κN)-5-(三氟甲基)苯基-κC]铱
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关于此项目
经验公式（希尔记法）:
C36H21F9IrN3
化学文摘社编号:
分子量:
858.77
MDL number:
UNSPSC Code:
12161600
NACRES:
NA.22
产品名称
Ir(p-CF3-ppy)3, ≥95%
SMILES string
[Ir]741([NH]8=C(c9c7cc(cc9)C(F)(F)F)C=CC=C8)([NH]5=C(c6c4cc(cc6)C(F)(F)F)C=CC=C5)[NH]2=C(c3c1cc(cc3)C(F)(F)F)C=CC=C2
InChI
1S/3C12H7F3N.Ir/c3*13-12(14,15)10-6-4-9(5-7-10)11-3-1-2-8-16-11;/h3*1-4,6-8H;
InChI key
ZLVNAIXHGHEODI-UHFFFAOYSA-N
assay
≥95%
form
powder or crystals
reaction suitability
core: iridium
reagent type: catalyst
reaction type: Photocatalysis
mp
>300 °C
photocatalyst activation
465 nm
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
A Singh et al.
Chemical science, 6(12), 7206-7212 (2015-12-01)
C-F functionalizations that provide C-C bonds are challenging synthetic transformations, due in part to the large C-F bond strength, short bond length, nonpolarizable nature, the production of fluoride, and the regioselectivity-in the case of multifluorinated substrates. However, commercially available highly
Facile synthesis and complete characterization of homoleptic and heteroleptic cyclometalated Iridium(III) complexes for photocatalysis
Singh A, et al.
Journal of Organometallic Chemistry, 776, 51-59 (2015)
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