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Merck
CN

90660

三苄胺

≥99.0% (NT)

别名:

TBA

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关于此项目

线性分子式:
(C6H5CH2)3N
化学文摘社编号:
分子量:
287.40
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-638-3
Beilstein/REAXYS Number:
2214682
MDL number:
Assay:
≥99.0% (NT)
Form:
powder
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assay

≥99.0% (NT)

form

powder

mp

91-94 °C (lit.)

functional group

amine, phenyl

SMILES string

C(N(Cc1ccccc1)Cc2ccccc2)c3ccccc3

InChI

1S/C21H21N/c1-4-10-19(11-5-1)16-22(17-20-12-6-2-7-13-20)18-21-14-8-3-9-15-21/h1-15H,16-18H2

InChI key

MXHTZQSKTCCMFG-UHFFFAOYSA-N

Application

三苄胺(TBA)是一种叔胺,可以用作:
  • 涉及 C−N 键形成反应的氮基源;
  • 用于通过有氧氧化缩合反应合成亚胺,即 N−亚苄基苄胺。
  • 作为萃取剂,用于分离和测定废水中的 Cr(VI)和Cr(III)。

TBA 还可以在硝酸铈铵(CAN)存在下进行脱苄基反应以形成二苄胺。


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pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Skin Sens. 1

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

399.2 °F - closed cup

flash_point_c

204 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Céline Burnier et al.
Talanta, 192, 135-141 (2018-10-24)
Nowadays, Gas Chromatography Mass Spectrometry (GC-MS) is mainly used in forensic sciences but suffers from limitations when the analysed compounds are thermally instable as it is the case for THC-A (Tetrahydrocannabinolic Acid) which is converted into Δ9-THC (Δ9-Tetrahydrocannabinol) that subsequently
Copper-Catalyzed Oxidative Amination of Benzoxazoles via C- H and C- N Bond Activation: A New Strategy for Using Tertiary Amines as Nitrogen Group Sources.
Guo S, et al.
Organic Letters, 13(3), 522-525 (2010)
Najat S Khan et al.
The Journal of organic chemistry, 76(5), 1418-1424 (2011-01-29)
A gyroscope-inspired tribenzylamine hemicryptophane provides a vehicle for exploring the structure and properties of multiple p-phenylene rotators within one molecule. The hemicryptophane was synthesized in three steps in good overall yield using mild conditions. Three rotator-forming linkers were cyclized to



全球贸易项目编号

货号GTIN
90660-100G04061835370016
90660-500G04061833247174