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Merck
CN

908711

Ni(IMes)(di-t-butyl fumarate)2

powder

别名:

Montgomery Ni catalyst

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关于此项目

经验公式(希尔记法):
C45H64N2NiO8
化学文摘社编号:
分子量:
819.69
MDL number:
UNSPSC Code:
12352103
NACRES:
NA.22
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产品名称

Ni(IMes)(di-t-butyl fumarate)2,

form

powder

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

SMILES string

[Ni].N2(CN(C=C2)c3c(cc(cc3C)C)C)c1c(cc(cc1C)C)C.O(C(C)(C)C)C(=O)\C=C\C(=O)OC(C)(C)C.O(C(C)(C)C)C(=O)\C=C\C(=O)OC(C)(C)C

InChI key

NAUZISBIAJSKIT-RKDKPBPFSA-N

Application

Ni(IMes)(di-t-butyl fumarate)2 is an NHC-Ni(0) precatalyst developed in the Montgomery lab used for a variety of synthetic transformations including reductive couplings of aldehydes and alkynes and N-arylation of amines.


存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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