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经验公式(希尔记法):
C25H26BF4N
化学文摘社编号:
分子量:
427.29
MDL number:
UNSPSC Code:
12352101
NACRES:
NA.22
产品名称
2,7-Dimethyl-9-mesityl-10-methylacridinium tetrafluoroborate,
InChI key
UCBSHEKJRRAYNP-UHFFFAOYSA-N
SMILES string
[B-](F)(F)(F)F.[n+]1(c2c(c(c4c1ccc(c4)C)c3c(cc(cc3C)C)C)cc(cc2)C)C
form
powder
reaction suitability
reaction type: Photocatalysis, reagent type: catalyst
Application
Robust acridinium-based photocatalyst reported by Nicewicz and coworkers as an alternative to transition-metal-based photocatalysts with higher chemical stability and attenuated redox potential.
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Dale J Wilger et al.
Nature chemistry, 6(8), 720-726 (2014-07-24)
The direct anti-Markovnikov addition of strong Brønsted acids to alkenes remains an unsolved problem in synthetic chemistry. Here, we report an efficient organic photoredox catalyst system for the addition of HCl, HF and also phosphoric and sulfonic acids to alkenes
相关内容
Nicewicz lab focuses on reactive cation radical species for selective reactions, advancing synthesis methodologies for various functional groups.
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