910724
PhPAd-DalPhos
≥95%, powder
别名:
8-(2-(Diphenylphosphaneyl)phenyl)-1,3,5,7-tetramethyl-2,4,6-trioxa-8-phosphaadamantane
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关于此项目
经验公式（希尔记法）:
C28H30O3P2
化学文摘社编号:
分子量:
476.48
MDL number:
UNSPSC Code:
12352002
NACRES:
NA.22
产品名称
PhPAd-DalPhos, ≥95%
assay
≥95%
form
powder
reaction suitability
reagent type: ligand
mp
193-194 °C
functional group
phosphine
SMILES string
P4(C5(OC6(OC(OC4(C6)C)(C5)C)C)C)c1c(cccc1)P(c3ccccc3)c2ccccc2
InChI
1S/C28H30O3P2/c1-25-19-27(3)31-26(2,29-25)20-28(4,30-25)33(27)24-18-12-11-17-23(24)32(21-13-7-5-8-14-21)22-15-9-6-10-16-22/h5-18H,19-20H2,1-4H3
InChI key
SWSJANGQMCPBHH-UHFFFAOYSA-N
Application
PhPAd-DalPhos is ligand developed in the Stradiotto lab that when combined with a Ni(II) source forms an air stable precatalyst for cross coupling of aryl electrophiles with bulky primary amines.
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable