912255
sBOX(tBu)
≥95%, powder or solid
别名:
Di-tert-butyl 2,2′-(cyclopropane-1,1-diyl)(4S,4′S)-bis(4,5-dihydrooxazole-4-carboxylate)
登录 查看组织和合同定价。
选择尺寸
关于此项目
经验公式（希尔记法）:
C19H28N2O6
化学文摘社编号:
分子量:
380.44
MDL number:
UNSPSC Code:
12352005
NACRES:
NA.22
产品名称
sBOX(tBu), ≥95%
SMILES string
N1=C(OC[C@H]1C(=O)OC(C)(C)C)C3(CC3)C2=N[C@@H](CO2)C(=O)OC(C)(C)C
InChI
1S/C19H28N2O6/c1-17(2,3)26-13(22)11-9-24-15(20-11)19(7-8-19)16-21-12(10-25-16)14(23)27-18(4,5)6/h11-12H,7-10H2,1-6H3/t11-,12-/m0/s1
InChI key
LKXTWWHADOFMCC-RYUDHWBXSA-N
assay
≥95%
form
powder or solid
mp
120.5 °C
storage temp.
2-8°C
Application
sBOX(tBu) is a serine-derived chiral bisoxazoline ligand. The additional coordinating functionality provided by the esters enables new reactivity compared to traditional BOX ligands. sBOX(iPr) has been shown to be an optimal ligand for the electrocatalytic cyanophosphorylation as well as hydrocyanation of vinylarenes.
Product can be used with our Synlectro electrochemistry platform (ESYNTH001)
Product can be used with our Synlectro electrochemistry platform (ESYNTH001)
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
此项目有
Niankai Fu et al.
Journal of the American Chemical Society, 141(37), 14480-14485 (2019-09-10)
In contrast to the rapid growth of synthetic electrochemistry in recent years, enantioselective catalytic methods powered by electricity remain rare. In this work, we report the development of a highly enantioselective method for the electrochemical cyanophosphinoylation of vinylarenes. A new
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持