form
liquid
Quality Level
functional group
ether
SMILES string
O1[C@@]2([C@H]1C[C@@H](CC2)C(=C)C)C
InChI
1S/C10H16O/c1-7(2)8-4-5-10(3)9(6-8)11-10/h8-9H,1,4-6H2,2-3H3/t8-,9-,10+/m1/s1
InChI key
CCEFMUBVSUDRLG-BBBLOLIVSA-N
Application
trans-(+)-Limonene oxide is a valuable chiral terpene oxide building block. Used in the synthesis of Phosphorus Incorporation (PI) reagents, as a biologically sourced component of polycarbonate polymers, and as a building block for synthetic applications requiring a reactive epoxide or alkene.
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
149.0 °F - closed cup
flash_point_c
65 °C - closed cup
Samantha A Green et al.
Journal of the American Chemical Society, 141(19), 7709-7714 (2019-04-30)
Metal-hydride hydrogen atom transfer (MHAT) functionalizes alkenes with predictable branched (Markovnikov) selectivity. The breadth of these transformations has been confined to π-radical traps; no sp3 electrophiles have been reported. Here we describe a Mn/Ni dual catalytic system that hydroalkylates unactivated
Ke-Yin Ye et al.
Journal of the American Chemical Society, 141(24), 9548-9554 (2019-06-11)
Organic radicals are generally short-lived intermediates with exceptionally high reactivity. Strategically, achieving synthetically useful transformations mediated by organic radicals requires both efficient initiation and selective termination events. Here, we report a new catalytic strategy, namely, bimetallic radical redox-relay, in the
Synthesis and self-assembly of biobased poly(limonene carbonate)-block-poly(cyclohexene carbonate) diblock copolymers prepared by sequential ring-opening copolymerization.
Bailer J, et al.
Green Chemistry, 21, 2266-2272 (2019)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 921459-5G | 04065266515459 |
| 921459-25G | 04065266515442 |