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经验公式(希尔记法):
C50H64ClNO6
化学文摘社编号:
分子量:
810.50
MDL number:
NACRES:
NA.23
UNSPSC Code:
12352200
description
Emissive Layer
Polymorph crystalline phase: Solid, Discotic Liquid Crystal, Isotropic
transition temp
discotic phase to isotropic phase 148 °C (heating)
crystalline phase to discotic phase 89 °C (heating)
solubility
soluble (THF > 1 mg/mL, MeCN < 0.63 mg/mL, DMSO < 0.43 mg/mL, DCM > 1 mg/mL)
λmax
271 nm in ethyl acetate
εmax
61,000 M-1cm-1 in ethyl acetate
fluorescence
λem 499 nm, quantum yield 0.53 (pSS(nm) = 228; Fluorescence lifetime (ns) = 6.49)
storage temp.
−20°C
Quality Level
Application
Fluorescent materials have a range of unique properties that allows for potential use in a range of applications:
- Fluorescent dye staining
- Organic semiconductor for organic electronic and photonic applications
- Multi-photon microscopy
Disclaimer
Storage: Store under nitrogen in the dark in the freezer (below 8 Celsius).
General description
TpOx-Ph-o-Cl is a UV excitable fluorescent material with a polycyclic aromatic donor-acceptor structure where the triphenoxazole core acts as a donor and the aromatic group on the two position of the oxazole (2-chloro-phenyl) act as the acceptor group. The push-pull, donor-acceptor, structure facilitates intramolecular charge transfer in the excited state that results in a 228 nm emission Stokes Shift. TpOx-Ph-o-Cl is also a photo-conducting Discotic Liquid Crystalline (DLC) material with mesophase transition onset temperature of 89°C. TpOx-Ph-o-Cl is designed for 355 nm and 405 nm excitation with emission at 499 nm with quantum yield of 0.53, high thermal, chemical and photostability. TpOx-Ph-o-Cl has potential uses in fluorescent dye staining, organic electronic and photonics, and imaging applications.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
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Triphenoxazoles exhibit tunable properties, liquid crystallinity, and potential for modification.
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