922943
TpOx-Ph-p-CF3
别名:
2,3,6,11,12-Pentakis(pentyloxy)-8-(4-(trifluoromethyl)phenyl)triphenyleno[1,2-d]oxazole, TpOx-Ph-CF3 Series
描述
Emissive Layer
Polymorph crystalline phase: Solid, Discotic Liquid Crystal, Isotropic
质量水平
带隙
2.94 eV (Optical, Solution state)
转变温度
crystalline phase to discotic phase 145 °C (heating)
isotropic phase to discotic phase 276 °C (cooling)
discotic phase to isotropic phase 281 °C (heating)
discotic phase to crystalline phase <74 °C (cooling)
溶解性
soluble (THF > 1 mg/mL, MeCN < 0.23 mg/mL, DMSO < 0.23 mg/mL, DCM > 1 mg /mL)
λmax
271 nm in ethyl acetate
ε (消光系数)
104,000 M-1cm-1
荧光
λem 526 nm, quantum yield 0.51 (pSS(nm) = 255; Fluorescence lifetime (ns) = 7.31)
轨道能量
HOMO -5.44 eV (CV)
LUMO -2.5 eV (CV)
储存温度
−20°C
一般描述
应用
- Fluorescent dye staining
- Organic semiconductor for organic electronic and photonic applications
制备说明
储存分类代码
11 - Combustible Solids
WGK
WGK 3
法规信息
商品
Triphenoxazoles exhibit tunable properties, liquid crystallinity, and potential for modification.
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