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Merck
CN

923192

Sigma-Aldrich

Spiro-TTB

greener alternative

≥99% (HPLC)

别名:

2,2′,7,7′- Tetrakis(N,N′-di-p-methylphenylamino)-9,9′-spirobifluorene, 2,2′,7,7′-Tetra(N, N-di-tolyl)amino-spiro-bifluorene, 2,2′,7,7′-Tetra(N,N-di-p-tolyl)amino-9,9-spirobifluorene, 2,2′,7,7′-Tetra(N,N-ditolylL)amino-9,9-spiro-bifluorene, 2,2′,7,7′-Tetrakis(di-p-tolylamino)-9,9′-spirobi[fluorene], 2,2′,7,7′-Tetrakis(di-p-tolylamino)spiro-9,9′-bifluorene, N2,N2,N2′,N2′,N7,N7,N7′,N7-Octa-p-tolyl-9,9′-spirobi[fluorene]-2,2′,7,7′-tetraamine

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About This Item

经验公式(希尔记法):
C81H68N4
CAS Number:
分子量:
1097.43
MDL编号:
UNSPSC代码:
41116105
NACRES:
NA.23

描述

PL:409 nm (in THF)
TGA:> 360 °C (0.5% weight loss)
Tg: 146 °C

质量水平

方案

≥99% (HPLC)

分子量

average mol wt 1097.43 g/mol

环保替代产品特性

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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缺失

0.5% TGA, >360°C

转变温度

Tg 146 °C

溶解性

THF: soluble

λmax

385 nm in THF

轨道能量

HOMO 5.2 eV 
LUMO 1.9 eV 

环保替代产品分类

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一般描述

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product belongs to enabling category of greener alternatives, and has been enhanced for energy efficiency. Click here for more information.

应用

Spiro-TTB is a high-mobility organic semiconductor with strong donor character given its four substituted arylamine moieties that stabilize positively charged cationic states via mesomeric effects.
It has been successfully applied as transparent hole-transparent layer in solar cells, organic field-effect transistors (OFETs), and organic light emitting devices (OLEDs). In photovoltaics, spiro-TTB was used as organic hole selective layer between perovskite and the silicon cells, contributing to a 25.2% efficency perovskite/ silicon tandem solar cell. When used in OLEDs, spiro-TTB enabled applications in organic photodetectors (OPDs), imaging and lasing applications.
Spiro-TTB is used as a hole transport material in OLED devices, organic photovoltaics (OPVs), organic field-effect transistors (OFETs) and perovskite solar cells. It exhibits excellent hole injection and transport properties, enabling efficient charge transport from the anode to the emitting layers of the OLED structure. This contributes to improved device performance, stability, and overall efficiency.

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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