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923478

CyMPhos

Name: CyMPhos
Brand: ALDRICH

别名:

1-Diadamantylphosphino-1′-dicyclohexylphosphinoferrocene

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关于此项目

经验公式（希尔记法）:

C₄₂H₆₀FeP₂

分子量:

682.72

UNSPSC Code:

12352200

NACRES:

NA.21

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属性

Quality Level

100

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings, reagent type: ligand

functional group

phosphine

SMILES string

c1(P(C2CCCCC2)C3CCCCC3)cccc1.c4(P([C@@]56C[C@@H](C[C@H]7C6)C[C@@H](C7)C5)[C@@]89C[C@@H](C[C@H]%10C9)C[C@@H](C%10)C8)cccc4.[Fe]

说明

Application

CyMPhos is an unsymmetrical ferrocene-based phosphine ligand. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. Pd catalysts containing CyMPhos can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp²-Csp³ coupling. Demonstrated Csp²-Csp³ couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR2)).

Learn more about MPhos ligands and catalysts

Other Notes

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp²–Csp³ Couplings

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

MKCR6480

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商品

MPhos Ligands & Catalysts

YPhos ligands facilitate palladium-catalyzed coupling reactions of aryl chlorides under mild conditions with short reaction times.

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp2?Csp3 Couplings

Guolin Xu, Peng Gao, and Thomas J. Colacot

ACS Catalysis, 12, 5123?5135-5123?5135 (2022)

全球贸易项目编号

货号	GTIN
923478-500MG	04065268454640
923478-100MG	04065268454633