产品名称
ItOct HCl, ≥95.0%
Quality Segment
assay
≥95.0%
form
powder
reaction suitability
reagent type: ligand
reaction type: Cross Couplings
parameter
moisture stable
SMILES string
CC(C)(CC(C)(C)C)N1C=[N+](C(C)(CC(C)(C)C)C)C=C1.[Cl-]
InChI
1S/C19H37N2.ClH/c1-16(2,3)13-18(7,8)20-11-12-21(15-20)19(9,10)14-17(4,5)6;/h11-12,15H,13-14H2,1-10H3;1H/q+1;/p-1
InChI key
USCUVFCUVMJDDA-UHFFFAOYSA-M
Application
ItOct HCl is an N-alkyl NHC ligand with demonstrated uses in the following reactions. Au-catalyzed hydration, Cu-catalyzed hydroboration, Ag-catalyzed hydroboration, Cu-catalyzed C–O coupling and Pd-catalyzed C–C and C–N couplings. This ligand features significantly higher steric volume compared with ItBu (659983) while maintaining the σ-donation and σ-acceptance inherent to N-alkyl NHC ligands.
存储类别
11 - Combustible Solids
wgk
WGK 3