930059
S-Phenyl methanethioate
别名:
Phenyl thioCORMate, Phenyl thioformate
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关于此项目
经验公式（希尔记法）:
C7H6OS
化学文摘社编号:
分子量:
138.19
UNSPSC Code:
12352101
NACRES:
NA.06
MDL number:
InChI
1S/C7H6OS/c8-6-9-7-4-2-1-3-5-7/h1-6H
InChI key
ITJOOMDVHPTIRB-UHFFFAOYSA-N
SMILES string
[H]C(SC1=CC=CC=C1)=O
form
liquid
refractive index
n/D 1.586
density
1.134 g/mL
functional group
thioether
storage temp.
−20°C
Quality Level
Application
S-phenyl methanethioate is an effective CO releasing molecule (CORM) developed by the lab of Sarah Tasker as part of a series of thioformate based CORMs called thioCORMates. p-NO2 phenyl thioformate generates CO over the course of several minutes to allow for on-demand generation of CO for variety of reactions.
This and the other thioCORMates are cost effective CORMs that when activated with simple amines, can be used to generate a near quantitative amount of CO safely without the usage of gas cylinders. These are compatible with a variety of carbonylation reactions, as well as existing COware glassware and components.
ThioCORMate: Tunable and Cost-Effective Carbon Monoxide-Releasing Molecule
Learn more about CO releasing molecules from Prof. Skrydstrup
This and the other thioCORMates are cost effective CORMs that when activated with simple amines, can be used to generate a near quantitative amount of CO safely without the usage of gas cylinders. These are compatible with a variety of carbonylation reactions, as well as existing COware glassware and components.
ThioCORMate: Tunable and Cost-Effective Carbon Monoxide-Releasing Molecule
Learn more about CO releasing molecules from Prof. Skrydstrup
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
221.0 °F
flash_point_c
105 °C
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The Tasker group's work focuses on the synthesis and utilization of stoichiometric CO-releasing molecules (CORMs) as alternatives to pressurized cylinders when the gas has safety, stability, or other practical handling concerns.
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