930202
3-(2,4,6-Trimethylbenzyl)-1-(2,6-diisopropylphenyl)-4,5-dimethylimidazolium chloride
≥95%, powder
别名:
3-(2,6-diisopropylphenyl)-4,5-dimethyl-1-(2,4,6-trimethylbenzyl)-1H-imidazol-3-ium chloride
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产品名称
3-(2,4,6-Trimethylbenzyl)-1-(2,6-diisopropylphenyl)-4,5-dimethylimidazolium chloride, ≥95%
Quality Segment
assay
≥95%
form
powder
reaction suitability
reagent type: ligand
reaction type: Cross Couplings
SMILES string
[Cl-].C=1C=C(C(=C(C1)C(C)C)[N+]2=CN(C(=C2C)C)CC=3C(=CC(=CC3C)C)C)C(C)C
InChI
1S/C27H37N2.ClH/c1-17(2)24-11-10-12-25(18(3)4)27(24)29-16-28(22(8)23(29)9)15-26-20(6)13-19(5)14-21(26)7;/h10-14,16-18H,15H2,1-9H3;1H/q+1;/p-1
InChI key
VEFYQHOVUBFLHY-UHFFFAOYSA-M
Application
3-(2,4,6-Trimethylbenzyl)-1-(2,6-diisopropylphenyl)-4,5-dimethylimidazolium chloride is a highly hindered and flexible unsymmetrical NHC ligand for hydrofunctionalization reactions. When combined with a group 11 metal (Cu, Au, Ag), this ligand can be used in hydroelement additions, element-element additions, carbo-element additions, hydrations, hydroaminations, hydroarylations, hyroalkoxylations, hydrocarboxylations, cyclizations, hydrofluorinations, as well as a variety of combined processes using tandem reactions.
警示词
Danger
Hazard Classifications
Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Sens. 1
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
闪点 (F)
Not applicable
闪点 (°C)
Not applicable