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Merck
CN

930458

OxMet2-alkyne

别名:

(3-Phenyl-1,2-oxaziridin-2-yl)(4-(prop-2-yn-1-yloxy)piperidin-1-yl)methanone

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关于此项目

经验公式(希尔记法):
C16H18N2O3
分子量:
286.33
MDL number:
UNSPSC Code:
12352101
NACRES:
NA.22
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description

Application: Chemoproteomics

Quality Level

form

liquid

storage temp.

−20°C

SMILES string

O=C(N1OC1C2=CC=CC=C2)N(CC3)CCC3OCC#C

InChI key

ZAZCIGLVVPPSLS-UHFFFAOYSA-N

Application

OxMet2-alkyne is an oxaziridine probe that can be used to label methionines. A method was developed using cysteine-reactive compounds including this one to allow for unbiased analysis of proteomic data in quantitative applications (Zanon et al. 2021). The method uses light or heavy labelling with the isotopically labelled desthiobiotin azide (isoDTB) tag for mass spectrometry analysis (Zanon et al. 2020). Analysis then uses the isotopic tandem orthogonal proteolysis activity-based protein profiling (isoTOP-ABPP) workflow (Weerapana et al. 2010, Backus et al. 2016)


存储类别

10 - Combustible liquids

flash_point_f

Not applicable

flash_point_c

Not applicable



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Profiling the proteome-wide selectivity of diverse electrophiles
Patrick R. A. Zanon, Fengchao Yu, et al
ChemRxiv : the preprint server for chemistry (2021)
Rui Sun et al.
Chemical research in toxicology, 30(10), 1797-1803 (2017-09-30)
Reactive metabolites (RM) formed from bioactivation of drugs can covalently modify liver proteins and cause mechanism-based inactivation of major cytochrome P450 (CYP450) enzymes. Risk of bioactivation of a test compound is routinely examined as part of lead optimization efforts in
Ping Yu et al.
Nucleosides, nucleotides & nucleic acids, 40(7), 754-766 (2021-06-29)
We report herein comprehensive investigations of alkylation/sulfur exchange reactions of sulfur-containing substrates including nucleosides such as s2U, m5s2U, s4U, s2A and s2T-incorporated DNA enable by comprehensive screenings of the reagents (2a-2h). It has been proven that iodoacetamide (2a) displays the



全球贸易项目编号

货号GTIN
930458-50MG04065268915899