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线性分子式:
MgCl2 · 6H2O
化学文摘社编号:
分子量:
203.30
UNSPSC Code:
12352302
NACRES:
NA.21
MDL number:
Assay:
99.999% (trace metals basis)
Form:
crystalline
Solubility:
H2O: soluble (highly soluble)
acetone: slightly soluble
alcohols: slightly soluble
acetone: slightly soluble
alcohols: slightly soluble
产品名称
氯化镁 六水合物, 99.999% (trace metals basis)
InChI
1S/2ClH.Mg.6H2O/h2*1H;;6*1H2/q;;+2;;;;;;/p-2
SMILES string
O.O.O.O.O.O.Cl[Mg]Cl
InChI key
DHRRIBDTHFBPNG-UHFFFAOYSA-L
assay
99.999% (trace metals basis)
form
crystalline
reaction suitability
core: magnesium
mp
117 °C
solubility
H2O: soluble (highly soluble)
acetone: slightly soluble
alcohols: slightly soluble
Quality Level
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Application
One major application of high-purity magnesium chloride is in the synthesis of layered double hydroxides (LDH), which are high-surface area ionic clays. LDHs are studied for water filtration, among other applications, and usually consist of magnesium and aluminum ions because of the low toxicity of these metal cations. LDHs are synthesized from chloride salts using co-precipitation reactions, ion-exchange processes, and urea methods. Another application of high-purity magnesium chloride is as a reagent to dope or substitute magnesium ions into solid-state materials and nanoparticles. For example, Mg-doping in ZnO has shown to modulate its band structure and Mg-doping in lithium nickel cobalt manganese oxide helps suppress cation mixing and enables longer cycle lifetimes for its use as a cathode material.
General description
Magnesium chloride hexahydrate is a colorless to white, crystalline salt. The salt is soluble in water and slightly soluble in ethanol, acetone, and pyridine. The hydrate loses water when heated to higher temperatures, but thermal dehydration to the anhydrous salt is not straightforward. Chemically, magnesium chloride is a weak Lewis acid. One of the most common and simplest routes to producing magnesium chloride is extraction from naturally occurring brine, for example by solar evaporation of sea water, which can be purified by solution chemistries.
存储类别
13 - Non Combustible Solids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
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Effect of Mg doping on the structural and electrochemical performance of LiNi0.6Co0.2Mn0.2O2 cathode materials
Huang, Z., Wang, Z., et al.
Electrochimica Acta, 795-802, 182-182 (2015)
Band gap engineering and enhanced photoluminescence of Mg doped ZnO nanoparticles synthesized by wet chemical route
Arshad, M., Ansari, M.M., et al.
Journal of Luminescence, 161, 275-280 (2015)
A New Approach for Removing Anionic Organic Dyes from Wastewater Based on Electrostatically Driven Assembly
Sansuk, S., Srijaranai, S., et al.
Environmental Science & Technology, 50, 6477?6484-6477?6484 (2016)
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