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Merck
CN

931837

(4R,4′R,5S,5′S)-2,2′-Cyclopropylidenebis[4,5-dihydro-4,5-diphenyloxazole]

greener alternative

≥95%, powder

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关于此项目

经验公式(希尔记法):
C33H28N2O2
化学文摘社编号:
分子量:
484.59
UNSPSC Code:
12352101
NACRES:
NA.22
MDL number:
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产品名称

(4R,4′R,5S,5′S)-2,2′-Cyclopropylidenebis[4,5-dihydro-4,5-diphenyloxazole], ≥95%

SMILES string

N1=C(O[C@H]([C@H]1c7ccccc7)c6ccccc6)C5(CC5)C2=N[C@@H]([C@@H](O2)c4ccccc4)c3ccccc3

InChI key

UAXGHJCFHMQPBJ-XAZDILKDSA-N

assay

≥95%

form

powder

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

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Quality Level

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

(4R,4′R,5S,5′S)-2,2′-Cyclopropylidenebis[4,5-dihydro-4,5-diphenyloxazole] is a bisoxazoline (BOX) ligand for asymmetric catalysis. The copper-ligand complex has been shown to catalyze reactions of symmetric diaziridines with enol diazo compounds.

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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分析证书(COA)

Lot/Batch Number

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Catalytic Desymmetric Cycloaddition of Diaziridines with Metalloenolcarbenes: The Role of Donor-Acceptor Cyclopropenes
Zheng H, et al.
Angewandte Chemie (International Edition in English), 58, 12502-12506 (2019)

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