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关于此项目
经验公式(希尔记法):
C33H28N2O2
化学文摘社编号:
分子量:
484.59
UNSPSC Code:
12352101
NACRES:
NA.22
MDL number:
产品名称
(4R,4′R,5S,5′S)-2,2′-Cyclopropylidenebis[4,5-dihydro-4,5-diphenyloxazole], ≥95%
SMILES string
N1=C(O[C@H]([C@H]1c7ccccc7)c6ccccc6)C5(CC5)C2=N[C@@H]([C@@H](O2)c4ccccc4)c3ccccc3
InChI key
UAXGHJCFHMQPBJ-XAZDILKDSA-N
assay
≥95%
form
powder
greener alternative product characteristics
Catalysis
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Quality Level
General description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
Application
(4R,4′R,5S,5′S)-2,2′-Cyclopropylidenebis[4,5-dihydro-4,5-diphenyloxazole] is a bisoxazoline (BOX) ligand for asymmetric catalysis. The copper-ligand complex has been shown to catalyze reactions of symmetric diaziridines with enol diazo compounds.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
此项目有
Catalytic Desymmetric Cycloaddition of Diaziridines with Metalloenolcarbenes: The Role of Donor-Acceptor Cyclopropenes
Zheng H, et al.
Angewandte Chemie (International Edition in English), 58, 12502-12506 (2019)
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