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关于此项目
经验公式(希尔记法):
C46H46N2
化学文摘社编号:
分子量:
626.87
UNSPSC Code:
12352103
NACRES:
NA.23
MDL number:
InChI
1S/C46H46N2/c1-34-8-20-40(21-9-34)47(41-22-10-35(2)11-23-41)44-28-16-38(17-29-44)46(32-6-5-7-33-46)39-18-30-45(31-19-39)48(42-24-12-36(3)13-25-42)43-26-14-37(4)15-27-43/h8-31H,5-7,32-33H2,1-4H3
SMILES string
Cc1ccc(cc1)N(c2ccc(C)cc2)c3ccc(cc3)C4(CCCCC4)c5ccc(cc5)N(c6ccc(C)cc6)c7ccc(C)cc7
InChI key
ZOKIJILZFXPFTO-UHFFFAOYSA-N
grade
sublimed grade
description
µh ≈ 1.0 x 10-3cm2V-1s-1, Hole Transport Layer
assay
≥97% (HPLC)
loss
0.5% TGA, >290°C (weigh loss)
mp
186 °C
solubility
THF: soluble, chloroform: soluble, toluene: soluble
λmax
305 nm±5 nm in THF
fluorescence
λem 370 nm±10 nm in dichloromethane
orbital energy
HOMO 5.5 eV , LUMO 2.0 eV
Quality Level
Application
Di-[4-(N,N-di-p-tolyl-amino)-phenyl]cyclohexane, also known as TAPC, is a solution-processable Hole Transport, Electron Blocking Layer (HTL / EBL) benzene compound material with a μh around 1.0 × 10−3 cm2 V−1 s−1. It has been explored in several optoelectronic devices, especially in diodes such as efficient and stable lead-free halide double perovskites diodes.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
此项目有
White light generation combining emissions from exciplex, excimer and electromer in TAPC-based organic light-emitting diodes
Yang, Shengyi et al.
Chemical Physics Letters, 484, 54-58 (2009)
All-small-molecule efficient white organic light-emitting diodes by multi-layer blade coating
Yeh C H, et al.
Organic Electronics, 13, 914-918 (2012)
Extremely Simplified, High-Performance, and Doping-Free White Organic Light-Emitting Diodes Based on a Single Thermally Activated Delayed Fluorescent Emitter
Luo, D. et al.
ACS Energy Letters, 3, 1531-1538 (2018)
Weixuan Zeng et al.
Advanced materials (Deerfield Beach, Fla.), 30(5) (2017-12-09)
The combination of rigid acridine donor and 1,8-naphthalimide acceptor has afforded two orange-red emitters of NAI-DMAC and NAI-DPAC with high rigidity in molecular structure and strongly pretwisted charge transfer state. Endowed with high photoluminescence quantum yields (ΦPL ), distinct thermally
Wei Li et al.
Angewandte Chemie (International ed. in English), 58(33), 11301-11305 (2019-06-14)
Blue thermally activated delayed fluorescence (TADF) emitters that can simultaneously achieve high efficiency in doped and nondoped organic light-emitting diodes (OLEDs) are rarely reported. Reported here is a strategy using a tri-spiral donor for such versatile blue TADF emitters. Impressively
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