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Merck
CN

933961

1,1,2,2-Tetrafluoroethyl 2,2,3,3-tetrafluoropropylether

greener alternative

≥99%, <=100 ppm acid, battery grade

别名:

1,1,2,2-Tetrafluoro-3-(1,1,2,2-tetrafluoroethoxy)propane, HFE-458, TTE

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关于此项目

经验公式(希尔记法):
C5H4F8O
化学文摘社编号:
分子量:
232.07
UNSPSC Code:
12352100
NACRES:
NA.21
MDL number:
PubChem Substance ID:
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产品名称

1,1,2,2-Tetrafluoroethyl 2,2,3,3-tetrafluoropropylether, ≥99%, <=100 ppm acid, battery grade

SMILES string

FC(F)(OCC(F)(F)C(F)F)C(F)F

InChI

1S/C5H4F8O/c6-2(7)4(10,11)1-14-5(12,13)3(8)9/h2-3H,1H2

InChI key

HCBRSIIGBBDDCD-UHFFFAOYSA-N

grade

battery grade

description

Application: Battery manufacturing

assay

≥99%

form

liquid

greener alternative product characteristics

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sustainability

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impurities

≤100 ppm Acid
≤100 ppm Non-volatile residue
≤750 ppm H2O

bp

92 °C

density

1.54 g/mL

application(s)

battery manufacturing

greener alternative category

Quality Level

Application

1,1,2,2-Tetrafluoroethyl 2,2,3,3-tetrafluoropropylether (TTE) is a highly versatile fluorinated ether that finds its use as a co-solvent and additive in a range of battery systems, including lithium-sulfur batteries (LSBs) and lithium-ion batteries (LiBs). In LSBs, TTE plays a crucial role in reducing the solubility of intermediate lithium polysulfides, thereby preventing the polysulfide shuttle (PSS) effect and improving battery performance. Recent research suggests that TTE can also lead to the formation of a compact and uniform surface layer on the lithium anode when used as an additive, which improves the efficiency and stability of Li-S batteries. In LiBs, TTE acts as a cosolvent, reducing the viscosity of the electrolyte and enabling the use of lower concentrations of lithium salt without compromising ionic conductivity. Additionally, TTE has been shown to help form a stable, conductive solid electrolyte interphase (SEI) on both graphite anodes and NMC cathodes, thereby improving the overall electrochemical performance of the battery.

General description

Our 1,1,2,2-tetrafluoroethyl 2,2,3,3-tetrafluoropropylether (TTE) is a high-purity, battery-grade fluorinated ether commonly used as an electrolyte solvent in lithium-ion batteries (LIBs). It is a clear liquid with a boiling point of 92 °C that is miscible with many polar organic solvents, including carbonates typically used in battery electrolytes. Our TTE is produced to meet the high standards of battery-grade purity, ensuring a minimum purity level of 99%, and is carefully purified to become anhydrous and acid-free, making it a reliable choice for battery applications.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Click here for more information.

pictograms

Flame

signalword

Warning

hcodes

Hazard Classifications

Flam. Liq. 3

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

80.6 °F - closed cup

flash_point_c

27 °C - closed cup

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Fluoro-Ether as a Bifunctional Interphase Electrolyte Additive with Graphite/LiNi0.5Co0.2Mn0.3O2 Full Cell
[3]Heng, et al.
ACS Applied Energy Materials, 2, 6404-6416 (2019)
Partially Fluorinated Ether as an Electrolyte Additive to Modify Electrode Surface and Suppress Dissolution of Polysulfides in Li-S Batteries
Qian, Feng
Electrochemical Energy Technology , 4 (2018)
Synthesis and electrochemical properties of partially fluorinated ether solvents for lithiumsingle bondsulfur battery electrolytes
Yue Zheng, et al.
Journal of Power Sources, 401, 271-277 (2018)

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