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Merck
CN

934003

Methyl (2,2,2-trifluoroethyl) carbonate

greener alternative

98%, anhydrous, battery grade

别名:

Carbonic Acid Methyl 2,2,2-Trifluoroethyl Ester, FEMC

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关于此项目

经验公式(希尔记法):
C4H5F3O3
化学文摘社编号:
分子量:
158.08
UNSPSC Code:
12352100
NACRES:
NA.21
MDL number:
PubChem Substance ID:
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产品名称

Methyl (2,2,2-trifluoroethyl) carbonate, 98%, anhydrous, battery grade

SMILES string

FC(F)(F)COC(=O)OC

InChI key

GBPVMEKUJUKTBA-UHFFFAOYSA-N

grade

battery grade

assay

98%

form

liquid

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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impurities

≤250 ppm HF
≤300 ppm H2O

bp

57-59 °C/120 mmHg
90 °C (lit.)

density

1.34 g/mL (lit.)

application(s)

battery manufacturing

greener alternative category

Quality Level

Application

Battery-grade methyl (2,2,2-trifluoroethyl) carbonate (FEMC) is an effective additive for improving the performance and stability of lithium-ion batteries. Its outstanding thermal and electrochemical stability makes it a reliable option for high-temperature and high-voltage battery applications. FEMC has been shown to improve battery life, enhance energy density, and increase cycling stability. As an electrolyte additive in lithium-ion batteries (LIBs), FEMC plays an important role in forming a stable solid electrolyte interphase (SEI) and effective passivation of the cathode surfaces, resulting in enhanced discharge capacity and cyclability. Even the addition of 5 wt % of FEMC was found to be very effective in forming a stable SEI layer and protecting the surface of the cathode. FEMC′s high performance makes it an attractive choice for battery manufacturers looking to create safe and efficient battery products.

General description

Methyl (2,2,2-trifluoroethyl) carbonate (FEMC), ≥99%, battery grade is one kind of fluorinated linear carbonate. It comes with very low water content (≤ 300.0 ppm) and low impurity of HF (≤ 250.0 ppm) which is ideal for battery research
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pictograms

FlameExclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

100.4 °F

flash_point_c

38 °C

法规信息

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Lot/Batch Number

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Building Safe Lithium-Ion Batteries for Electric Vehicles: A Review
Duan J, et al.
Electrochemical Energy Reviews, 3, 1-42 (2020)
Interfacial Origin of Performance Improvement and Fade for 4.6 V. LiNi0.5Co0.2Mn0.3O2 Battery Cathodes
Lee Yu-Mi, et al.
The Journal of Physical Chemistry C, 118, 10631?10639-10631?10639 (2014)
Fluorinated Carbonate-Based Electrolyte for High-Voltage Li(Ni0.5Mn0.3Co0.2)O2/Graphite Lithium-Ion Battery
Jinsol Im, et al.
Journal of the Electrochemical Society, 164 (2017)

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