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Merck
CN

935646

1,3,2-二噁唑噻吩-2,2-二氧化物

greener alternative

≥99%, anhydrous, battery grade

别名:

1,3,2-Dioxathiolane 2,2-dioxide, DTD

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关于此项目

经验公式(希尔记法):
C2H4O4S
化学文摘社编号:
分子量:
124.12
UNSPSC Code:
12352005
MDL number:
NACRES:
MA.24
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Quality Level

grade

anhydrous, battery grade

assay

≥99%

form

powder

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

impurities

≤750 ppm (H2O)

bp

231 °C

mp

95-97 °C (lit.)

application(s)

battery manufacturing

greener alternative category

storage temp.

2-8°C

SMILES string

O=S1(=O)OCCO1

InChI

1S/C2H4O4S/c3-7(4)5-1-2-6-7/h1-2H2

InChI key

ZPFAVCIQZKRBGF-UHFFFAOYSA-N

General description

Ethylene sulfate (DTD) is a polar cyclic sulfate ester. It is a white powder that is soluble in many of the polar organic solvents used in battery applications, including carbonates. Our battery grade ethylene sulfate is differentiated by its high purity, low trace water content, and low trace acid content, which avoid unwanted chemical reactions with the anode and increase capacity, safety, and life span in batteries

Application

Ethylene sulfate has a range of industrial applications. Our anhydrous battery grade ethylene sulfate is primarily used as an electrolyte additive to extend the lifetime of lithium-ion batteries and sodium-ion batteries.[,] Ethylene sulfate helps to improve the formation of a stable solid-electrolyte interphase (SEI) on the surface of the anode material, which can prevent reaction between the anode and the electrolyte, leading to better battery lifespan and more stable impedance across the interphase.[] DTD is often used in conjunction with other additives. One of the best-performing electrolyte formulations for graphite cells is a 1.0 M LiPF6 in a carbonate blend with 1% DTD and 2%VC.[,]


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Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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商品

Discover the role of electrolytes in sodium-ion batteries, to enhance performance, safety, and sustainability in energy storage solutions.


Ethylene sulfate as film formation additive to improve the compatibility of graphite electrode for lithium-ion battery
Xuecheng L, et al.
Ionics, 20, 795-801 (2014)
Ethylene sulfate as film formation additive to improve the compatibility of graphite electrode for lithium-ion battery
Xuecheng L, et al.
Ionics, 20, 795-801 (2014)
Comparative study of 1,3-propane sultone, prop-1-ene-1,3-sultone and ethylene sulfate as film-forming additives for sodium ion batteries
Zhang Q, et al.
Journal of Power Sources, 541, 231726-231726 (2022)



全球贸易项目编号

货号GTIN
935646-25G04065270539175