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线性分子式:
[(CH3)3SiO]3B
化学文摘社编号:
分子量:
278.38
NACRES:
MA.24
UNSPSC Code:
12352005
Beilstein/REAXYS Number:
1772733
MDL number:
Assay:
≥99.5%
Grade:
battery grade
Form:
(Colorless liquid)
产品名称
三(三甲代甲硅烷基)硼酸盐, ≥99.5%, battery grade
SMILES string
C[Si](C)(C)OB(O[Si](C)(C)C)O[Si](C)(C)C
InChI
1S/C9H27BO3Si3/c1-14(2,3)11-10(12-15(4,5)6)13-16(7,8)9/h1-9H3
InChI key
YZYKZHPNRDIPFA-UHFFFAOYSA-N
grade
battery grade
description
Application: Battery manufacturing
assay
≥99.5%
form
(Colorless liquid)
greener alternative product characteristics
Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.
sustainability
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refractive index
n20/D 1.386 (lit.)
bp
186 °C (lit.)
186 °C
mp
-35 °C
density
0.831 g/mL at 25 °C (lit.)
application(s)
battery manufacturing
greener alternative category
Quality Level
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Application
Tris(trimethylsilyl) borate has a wide range of applications in various industries, including battery manufacturing, where it is used as an electrolyte additive, particularly in high-voltage lithium-ion batteries. TMSB is a cathode-film-forming additive that forms a thin protective coating called a solid-electrolyte interface (SEI) on the surface of the cathode. Adding TMSB to the electrolyte formulation, even at low concentrations of 0.5 wt.%, noticeably improves capacity retention for NMC, LMO, and LMNO cathodes. TMSB also is shown to reduce the flammability of the electrolyte and improve the thermal stability of LiPF6-based electrolytes at elevated temperatures.
TMSB also has catalytic properties, which make it useful in organic synthesis reactions and as a reagent in the manufacturing of pharmaceuticals and other chemicals.
TMSB also has catalytic properties, which make it useful in organic synthesis reactions and as a reagent in the manufacturing of pharmaceuticals and other chemicals.
General description
Tris(trimethylsilyl) borate (TMSB) is an electron-deficient organoborate compound. It is a colorless liquid that that is miscible with many organic solvents, including the linear and cyclic carbonates used in battery applications. Our battery grade TMSB is differentiated by its high purity and low trace water content to ensure consistent and reliable performance in batteries.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Click here for more information.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
105.8 °F - closed cup
flash_point_c
41 °C - closed cup
法规信息
新产品
此项目有
Effect of tris(trimethylsilyl)borate on the high voltage capacity retention of LiNi0.5Co0.2Mn0.3O2/graphite cells
Zuo X, et al.
Journal of Power Sources, 229, 308-312 (2013)
Tris(trimethylsilyl)borate as an electrolyte additive for improving interfacial stability of high voltage layered lithium-rich oxide cathode/carbonate-based electrolyte
Li J, et al
Journal of Power Sources, 285, 360-366 (2015)
Tris(trimethylsilyl) borate as an electrolyte additive to improve the cyclability of LiMn2O4cathode for lithium-ion battery
Liu Y, et al.
Journal of Power Sources, 221, 90-96 (2013)
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