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Merck
CN

935689

七水合硫酸亚铁(II)

greener alternative

99.99% trace metals basis

别名:

Iron(II) sulfate heptahydrate, Ferrous sulfate heptahydrate, Iron sulphate

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关于此项目

经验公式(希尔记法):
FeSO4 · 7H2O
化学文摘社编号:
分子量:
278.01
UNSPSC Code:
12352311
NACRES:
NA.21
MDL number:
Assay:
99.99% trace metals basis
Form:
powder or crystals (or granules)
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产品名称

七水合硫酸亚铁(II), 99.99% trace metals basis

SMILES string

[Fe+2].[S](=O)(=O)([O-])[O-].O.O.O.O.O.O.O

InChI

1S/Fe.H2O4S.7H2O/c;1-5(2,3)4;;;;;;;/h;(H2,1,2,3,4);7*1H2/q+2;;;;;;;;/p-2

InChI key

SURQXAFEQWPFPV-UHFFFAOYSA-L

assay

99.99% trace metals basis

form

powder or crystals (or granules)

reaction suitability

core: iron

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sustainability

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color

light blue to green

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storage temp.

2-30°C

Quality Level

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Application

Iron(II) sulfate heptahydrate, 99.99% trace metal basis is widely used in the synthesis of iron oxide, core shell Fe-Fe3O4 Nanostructures. These nanostructures were successfully used to trigger the sulphate radical oxidation of methyl orange (MO) in an aqueous solution by activating sodium persulfate. In addition, zero-valent iron is also used is also used as caatalyst for Fenton oxidation 2,4-dichlorophenol . Iron(II) sulfate heptahydrate is used as a catalyst for greener amide bond formation from amines and aldehydes. Moreover, iron(II) sulfate heptahydrate has been also used as an inexpensive and environmentally friendly catalyst, at room temperature for the four component Synthesis of Protected Homoallylic Amines. Iron(II) sulfate heptahydrate is also used as an important precursor for the synthesis of electrode materials for Battery. For example: The monoclinic form of FeOHSO4, synthesised from Iron(II)sulfate heptahydrate, has been used as a positive electrode material for rechargeable Li-ion batteries. In addition, Iron based flurophophate synthesised from Iron(II)sulfate heptahydrate also used as battery materials to increase the open-circuit voltage by manipulation of the oxidation state of 3d-metal through the electric effect of polyanion.

General description

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Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2

存储类别

11 - Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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历史批次信息供参考:

分析证书(COA)

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FeSO4?7H2O-Catalyzed Four-Component Synthesis of Protected Homoallylic Amines
Song, Qi-Yi
The Journal of Organic Chemistry, 72 (2007)
Monoclinic iron hydroxy sulphate: A new route to electrode materials
Reddy, M. Anji
Electrochemistry Communications, 11 (2009)
A 3.90 V iron-based fluorosulphate material for lithium-ion batteries crystallizing in the triplite structure
Barpanda, P.
Nature Materials, 10 (2011)
Core?shell Fe?Fe2O3 nanostructures as effective persulfate activator for degradation of methyl orange
Zhu, Linli
Separation and Purification Technology, 108 (2013)
Iron-Catalyzed Efficient Synthesis of Amides from Aldehydes and Amine Hydrochloride Salts
Ghosh, Chandra Subhash
Advanced Synthesis & Catalysis, 354 (2012)

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