938726
ImPy-Dipop-Dipp
powder
别名:
5-(2,6-diisopropoxyphenyl)-2-(2,6-diisopropylphenyl)imidazo[1,5-a]pyridin-2-ium chloride
产品名称
ImPy-Dipop-Dipp,
表单
powder
质量水平
反应适用性
reaction type: Cross Couplings
环保替代产品特性
Catalysis
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颜色
white
环保替代产品分类
SMILES字符串
CC(C1=CC=CC(C(C)C)=C1[N+]2=CN3C(C4=C(OC(C)C)C=CC=C4OC(C)C)=CC=CC3=C2)C.[Cl-]
InChI
1S/C31H39N2O2.ClH/c1-20(2)25-13-10-14-26(21(3)4)31(25)32-18-24-12-9-15-27(33(24)19-32)30-28(34-22(5)6)16-11-17-29(30)35-23(7)8;/h9-23H,1-8H3;1H/q+1;/p-1
InChI key
XMDMIAJKGFBECK-UHFFFAOYSA-M
一般描述
ImPy-Dipop-Dipp is an NHC precursor developed in the Szostak group. The ligand is useful in a range of catalytic transformations, and is particulary well suited to the following: Suzuki-Miyaura cross-coupling of aryl mesylates and tosylates, Suzuki–Miyaura cross-coupling of nitroarenes (Ar–NO2), Buchwald-Hartwig amination of alkyl sulfoxides
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应用
Suzuki-Miyaura cross-coupling of aryl mesylates and tosylates Suzuki–Miyaura cross-coupling of nitroarenes (Ar–NO2) or aryl sulfamates Buchwald-Hartwig amination of alkyl sulfoxides or aryl sulfamates
特点和优势
ImPy-Dipop-Dipp is an asymmetric NHC ligand precursor. It forms air-and moisture stable complexes with transition metals and is particulary effective in palladium catalyzed cross-coupling reactions.
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
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